Synthesis, solution stability, and structural characterization of quinolinol-based silver(I) complexes

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F20%3A00537741" target="_blank" >RIV/68378271:_____/20:00537741 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216208:11310/20:10412428

Výsledek na webu

<a href="https://doi.org/10.1080/00958972.2020.1758681" target="_blank" >https://doi.org/10.1080/00958972.2020.1758681</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1080/00958972.2020.1758681" target="_blank" >10.1080/00958972.2020.1758681</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis, solution stability, and structural characterization of quinolinol-based silver(I) complexes

Popis výsledku v původním jazyce

Three silver(I) complex compounds of halogen derivatives of 8-quinolinol (XQ), [Ag(HdClQ)2](NO3).CH3OH (1), [Ag(HdBrQ)2](NO3)(2), and [Ag(BrQ)]n(3), have been prepared with the aim to study their anticancer properties. All compounds were characterized by IR and NMR spectroscopy andelemental analysis. Single-crystal X-ray diffraction analysis revealed that crystal structure of1is ionic,2is molecular while 3 is polymeric. All three XQ ligands in 1–3 are N,O-chelate coordinated to the Ag(I) central atoms which are in a deformed square planar (1), distorted tetragonal pyramidal (2), or distorted triangular arrangement (3). Stability of all compounds in DMSO was proved by 1HNMR and UV-vis spectroscopy. Biological activity has not been studied because of limited solubility of prepared compounds in DMSO/water mixture.

Název v anglickém jazyce

Synthesis, solution stability, and structural characterization of quinolinol-based silver(I) complexes

Popis výsledku anglicky

Three silver(I) complex compounds of halogen derivatives of 8-quinolinol (XQ), [Ag(HdClQ)2](NO3).CH3OH (1), [Ag(HdBrQ)2](NO3)(2), and [Ag(BrQ)]n(3), have been prepared with the aim to study their anticancer properties. All compounds were characterized by IR and NMR spectroscopy andelemental analysis. Single-crystal X-ray diffraction analysis revealed that crystal structure of1is ionic,2is molecular while 3 is polymeric. All three XQ ligands in 1–3 are N,O-chelate coordinated to the Ag(I) central atoms which are in a deformed square planar (1), distorted tetragonal pyramidal (2), or distorted triangular arrangement (3). Stability of all compounds in DMSO was proved by 1HNMR and UV-vis spectroscopy. Biological activity has not been studied because of limited solubility of prepared compounds in DMSO/water mixture.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Projekt

<a href="/cs/project/LO1603" target="_blank" >LO1603: Centrum technologie a pokročilé strukturní analýzy aplikačně významných materiálů</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Coordination Chemistry

ISSN

0095-8972

e-ISSN

—

Svazek periodika

73

Číslo periodika v rámci svazku

5

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

15

Strana od-do

784-798

Kód UT WoS článku

000534122400001

EID výsledku v databázi Scopus

2-s2.0-85084845713