Formation of a copper-copper bond in coordination of a cyclotriphosphazene ligand toward Cu(II): Structural, spectral and docking studies

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F20%3A00537792" target="_blank" >RIV/68378271:_____/20:00537792 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.1016/j.molstruc.2020.127804" target="_blank" >https://doi.org/10.1016/j.molstruc.2020.127804</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.molstruc.2020.127804" target="_blank" >10.1016/j.molstruc.2020.127804</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Formation of a copper-copper bond in coordination of a cyclotriphosphazene ligand toward Cu(II): Structural, spectral and docking studies

Popis výsledku v původním jazyce

Two cyclotriphosphazene compounds, [HMPAP]2[SO4].2CH3OH (1), and [Cu(μ-OAc)2(MPAP)]2 (2), were prepared and identified by elemental analysis, FT-IR, Raman spectroscopy and single-crystal X-ray diffraction. In the crystal structure of 1, one nitrogen atom of the cyclotriphosphazene ring has been protonated. The copper complex (2) is binuclear formed by four bridging acetato ligands containing one Cu-Cu bond in the center of the complex. Each copper atom has a Cu(O4NCu) environment with octahedral geometry which is distorted owing to the Jahn-Teller effect. In the crystal network of the compounds, in addition to hydrogen bonds and hydrogen bond motifs (only in 1), p-p stacking interactions between phenyl rings further stabilize the crystal network.n

Název v anglickém jazyce

Formation of a copper-copper bond in coordination of a cyclotriphosphazene ligand toward Cu(II): Structural, spectral and docking studies

Popis výsledku anglicky

Two cyclotriphosphazene compounds, [HMPAP]2[SO4].2CH3OH (1), and [Cu(μ-OAc)2(MPAP)]2 (2), were prepared and identified by elemental analysis, FT-IR, Raman spectroscopy and single-crystal X-ray diffraction. In the crystal structure of 1, one nitrogen atom of the cyclotriphosphazene ring has been protonated. The copper complex (2) is binuclear formed by four bridging acetato ligands containing one Cu-Cu bond in the center of the complex. Each copper atom has a Cu(O4NCu) environment with octahedral geometry which is distorted owing to the Jahn-Teller effect. In the crystal network of the compounds, in addition to hydrogen bonds and hydrogen bond motifs (only in 1), p-p stacking interactions between phenyl rings further stabilize the crystal network.n

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Molecular Structure

ISSN

0022-2860

e-ISSN

—

Svazek periodika

1207

Číslo periodika v rámci svazku

May

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

9

Strana od-do

1-9

Kód UT WoS článku

000517790600032

EID výsledku v databázi Scopus

2-s2.0-85078697488