Synthesis and structural characterization of phosphinate coordination polymers with tin(IV) and copper(II)

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F20%3A00537795" target="_blank" >RIV/68378271:_____/20:00537795 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.1016/j.molstruc.2019.127369" target="_blank" >https://doi.org/10.1016/j.molstruc.2019.127369</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.molstruc.2019.127369" target="_blank" >10.1016/j.molstruc.2019.127369</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis and structural characterization of phosphinate coordination polymers with tin(IV) and copper(II)

Popis výsledku v původním jazyce

In this work, we report the synthesis and X-ray characterization of diphenylphosphinic acid (L) and its two polymeric phosphinate complexes, [(C6H5)2P(O)OSn(C6H5)3]n (C1) and [Cu(O2PPh2)2]n (C2), resulted from the bidentate coordinatioan of L. Sn(IV) centers in C1 are five-coordinate in a distorted trigonal bipyramidal geometry. One dimensional coordination chains of C2 are made by double-bridging ligands between the copper atoms, surrounded with four P-O in a square planar polyhedron. Structural characterization of the complexes revealed that M-O bonds are responsible for the assembly of the pri mary structural motifs in both the complexes while C-H … p and H/H interactions are effective in organizing these molecules into extended 3D architectures. The quantitative mapping of interactions was also analyzed using Hirshfeld surface analysis.

Název v anglickém jazyce

Synthesis and structural characterization of phosphinate coordination polymers with tin(IV) and copper(II)

Popis výsledku anglicky

In this work, we report the synthesis and X-ray characterization of diphenylphosphinic acid (L) and its two polymeric phosphinate complexes, [(C6H5)2P(O)OSn(C6H5)3]n (C1) and [Cu(O2PPh2)2]n (C2), resulted from the bidentate coordinatioan of L. Sn(IV) centers in C1 are five-coordinate in a distorted trigonal bipyramidal geometry. One dimensional coordination chains of C2 are made by double-bridging ligands between the copper atoms, surrounded with four P-O in a square planar polyhedron. Structural characterization of the complexes revealed that M-O bonds are responsible for the assembly of the pri mary structural motifs in both the complexes while C-H … p and H/H interactions are effective in organizing these molecules into extended 3D architectures. The quantitative mapping of interactions was also analyzed using Hirshfeld surface analysis.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Molecular Structure

ISSN

0022-2860

e-ISSN

—

Svazek periodika

1202

Číslo periodika v rámci svazku

Feb

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

9

Strana od-do

1-9

Kód UT WoS článku

000501486700098

EID výsledku v databázi Scopus

2-s2.0-85075379555