New heterobimetallic Cu(II)/Mn(II) complexes with trans-1,8-cyclam derivatives: Synthesis, characterization, magnetic properties and crystal structures of (µ2-Chloro)-(dpc)-copper(II)-trichloro-manganese(II) and two polymorphs of (µ2-Chloro)-(dac)-copper(II)-trichloro-manganese(II)
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F21%3A00542875" target="_blank" >RIV/68378271:_____/21:00542875 - isvavai.cz</a>
Výsledek na webu
<a href="https://doi.org/10.1016/j.molstruc.2021.130592" target="_blank" >https://doi.org/10.1016/j.molstruc.2021.130592</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2021.130592" target="_blank" >10.1016/j.molstruc.2021.130592</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
New heterobimetallic Cu(II)/Mn(II) complexes with trans-1,8-cyclam derivatives: Synthesis, characterization, magnetic properties and crystal structures of (µ2-Chloro)-(dpc)-copper(II)-trichloro-manganese(II) and two polymorphs of (µ2-Chloro)-(dac)-copper(II)-trichloro-manganese(II)
Popis výsledku v původním jazyce
Two derivatives of cyclam (cyclam = 1,4,8,11-tetraazacyclotetradecane) with propyl- or allyl- (prop-2-en-1-yl) substituents on nitrogen atoms in trans positions, namely 1,8-dipropyl-1,4,8,11- tetraazacyclotetradecane (dpc) and 1,8-diallyl-1,4,8,11-tetraazacyclotetradecane (dac) were prepared and characterized by IR, 1H NMR and 13C NMR spectroscopy. Reaction of dpc and dac with copper(II) chloride gives compounds [Cu(dpc)(H2O)22]Cl2 (1) and [Cu(dac)(H2O)2]Cl2 (3) with similar crystal structures. Compounds 1 and 3 were used as precursors in the synthesis of Cu(II)/Mn(II) complexes 2, 4a and 4b . Pre pared complexes were characterized by IR spectroscopy, elemental analysis and their crystal structures were determined using single crystal X-ray analysis.
Název v anglickém jazyce
New heterobimetallic Cu(II)/Mn(II) complexes with trans-1,8-cyclam derivatives: Synthesis, characterization, magnetic properties and crystal structures of (µ2-Chloro)-(dpc)-copper(II)-trichloro-manganese(II) and two polymorphs of (µ2-Chloro)-(dac)-copper(II)-trichloro-manganese(II)
Popis výsledku anglicky
Two derivatives of cyclam (cyclam = 1,4,8,11-tetraazacyclotetradecane) with propyl- or allyl- (prop-2-en-1-yl) substituents on nitrogen atoms in trans positions, namely 1,8-dipropyl-1,4,8,11- tetraazacyclotetradecane (dpc) and 1,8-diallyl-1,4,8,11-tetraazacyclotetradecane (dac) were prepared and characterized by IR, 1H NMR and 13C NMR spectroscopy. Reaction of dpc and dac with copper(II) chloride gives compounds [Cu(dpc)(H2O)22]Cl2 (1) and [Cu(dac)(H2O)2]Cl2 (3) with similar crystal structures. Compounds 1 and 3 were used as precursors in the synthesis of Cu(II)/Mn(II) complexes 2, 4a and 4b . Pre pared complexes were characterized by IR spectroscopy, elemental analysis and their crystal structures were determined using single crystal X-ray analysis.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Návaznosti výsledku
Projekt
<a href="/cs/project/LM2018110" target="_blank" >LM2018110: Výzkumná infrastruktura CzechNanoLab</a><br>
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Ostatní
Rok uplatnění
2021
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Journal of Molecular Structure
ISSN
0022-2860
e-ISSN
1872-8014
Svazek periodika
1241
Číslo periodika v rámci svazku
Oct
Stát vydavatele periodika
NL - Nizozemsko
Počet stran výsledku
10
Strana od-do
130592
Kód UT WoS článku
000664754100007
EID výsledku v databázi Scopus
2-s2.0-85107803576