Isostructural crystals of bis(guanidinium) trioxofluoro-phosphate/phosphite in the ratio 1/0, 0.716/0.284, 0.501/0.499, 0.268/0.732, 0/1—crystal structures, vibrational spectra and second harmonic generation

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F22%3A00564664" target="_blank" >RIV/68378271:_____/22:00564664 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216208:11310/22:10452472

Výsledek na webu

<a href="https://hdl.handle.net/11104/0336314" target="_blank" >https://hdl.handle.net/11104/0336314</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/cryst12121694" target="_blank" >10.3390/cryst12121694</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Isostructural crystals of bis(guanidinium) trioxofluoro-phosphate/phosphite in the ratio 1/0, 0.716/0.284, 0.501/0.499, 0.268/0.732, 0/1—crystal structures, vibrational spectra and second harmonic generation

Popis výsledku v původním jazyce

The title structures of bis(guanidinium) trioxofluorophosphate, bis(guanidinium) trioxofluorophosphate-phosphite (0.716/0.284), bis(guanidinium) trioxofluorophosphate-phosphite (0.501/0.499), bis(guanidinium) trioxofluorophosphate-phosphite (0.268/0.732), and bis(guanidinium) phosphite are crystal-chemically isotypic. The P and O atoms of the substituted trioxofluorophosphate and phosphite anions share the same positions while the P-F and P-H hydrido are almost parallel and oriented in the same direction. Two symmetry-independent anions and two of three symmetry-independent cations are situated on the crystallographic mirror planes. The ions are interconnected by N-H O hydrogen bonds of moderate strength. The title crystals were also characterized by FTIR and FT Raman and the second harmonic generation (SHG). The relative SHG efficiency considerably decreases from bis(guanidinium) trioxofluorophosphate to bis(guanidinium) phosphite for the fundamental 1064 nm laser line.n

Název v anglickém jazyce

Isostructural crystals of bis(guanidinium) trioxofluoro-phosphate/phosphite in the ratio 1/0, 0.716/0.284, 0.501/0.499, 0.268/0.732, 0/1—crystal structures, vibrational spectra and second harmonic generation

Popis výsledku anglicky

The title structures of bis(guanidinium) trioxofluorophosphate, bis(guanidinium) trioxofluorophosphate-phosphite (0.716/0.284), bis(guanidinium) trioxofluorophosphate-phosphite (0.501/0.499), bis(guanidinium) trioxofluorophosphate-phosphite (0.268/0.732), and bis(guanidinium) phosphite are crystal-chemically isotypic. The P and O atoms of the substituted trioxofluorophosphate and phosphite anions share the same positions while the P-F and P-H hydrido are almost parallel and oriented in the same direction. Two symmetry-independent anions and two of three symmetry-independent cations are situated on the crystallographic mirror planes. The ions are interconnected by N-H O hydrogen bonds of moderate strength. The title crystals were also characterized by FTIR and FT Raman and the second harmonic generation (SHG). The relative SHG efficiency considerably decreases from bis(guanidinium) trioxofluorophosphate to bis(guanidinium) phosphite for the fundamental 1064 nm laser line.n

Druh

J_SC - Článek v periodiku v databázi SCOPUS

CEP obor

—

OECD FORD obor

10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Projekt

<a href="/cs/project/EF15_003%2F0000417" target="_blank" >EF15_003/0000417: Centrum pro cílenou syntézu a aplikace perspektivních materiálů</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Crystals

ISSN

2073-4352

e-ISSN

2073-4352

Svazek periodika

12

Číslo periodika v rámci svazku

12

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

16

Strana od-do

1694

Kód UT WoS článku

000902397200001

EID výsledku v databázi Scopus

2-s2.0-85144682285