Pentacoordinate mixed-ligand Zn(II) complexes with flufenamato and niflumato ligands: crystal structure, spectral characterization and biological properties

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F23%3A00577700" target="_blank" >RIV/68378271:_____/23:00577700 - isvavai.cz</a>

Výsledek na webu

<a href="https://hdl.handle.net/11104/0346821" target="_blank" >https://hdl.handle.net/11104/0346821</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/cryst13101460" target="_blank" >10.3390/cryst13101460</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Pentacoordinate mixed-ligand Zn(II) complexes with flufenamato and niflumato ligands: crystal structure, spectral characterization and biological properties

Popis výsledku v původním jazyce

Mixed-ligand complexes featuring a carboxylato ligand and bidentate chelate N,N'-donor ligands along with a single halogenido ligand are rarely subjected to studies despite their interesting physical, chemical and biological properties. A direct synthesis involving non-steroidal anti-inflammatory drugs flufenamic acid and niflumic acid and sterically hindering N,N'-donor ligands (neocuproine and 2,2'-biquinoline) has been used to prepare mononuclear mixed-ligand zinc complexes with a composition of [ZnCl(flu)(neo)] (1A and 1B) and [ZnCl(nif )(biq)] (2). Single-crystal X-ray diffraction data have shown that the carboxylate binding mode differs in the two polymorphs 1A and 1B, which form molecules of same composition, and the deviations in molecular geometry are further reflected in their supramolecular structures.

Název v anglickém jazyce

Pentacoordinate mixed-ligand Zn(II) complexes with flufenamato and niflumato ligands: crystal structure, spectral characterization and biological properties

Popis výsledku anglicky

Mixed-ligand complexes featuring a carboxylato ligand and bidentate chelate N,N'-donor ligands along with a single halogenido ligand are rarely subjected to studies despite their interesting physical, chemical and biological properties. A direct synthesis involving non-steroidal anti-inflammatory drugs flufenamic acid and niflumic acid and sterically hindering N,N'-donor ligands (neocuproine and 2,2'-biquinoline) has been used to prepare mononuclear mixed-ligand zinc complexes with a composition of [ZnCl(flu)(neo)] (1A and 1B) and [ZnCl(nif )(biq)] (2). Single-crystal X-ray diffraction data have shown that the carboxylate binding mode differs in the two polymorphs 1A and 1B, which form molecules of same composition, and the deviations in molecular geometry are further reflected in their supramolecular structures.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Projekt

<a href="/cs/project/LM2023065" target="_blank" >LM2023065: Laboratoř pro syntézu a měření materiálů</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Crystals

ISSN

2073-4352

e-ISSN

2073-4352

Svazek periodika

13

Číslo periodika v rámci svazku

10

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

18

Strana od-do

1460

Kód UT WoS článku

001092489900001

EID výsledku v databázi Scopus

2-s2.0-85175186514