Fragmented charged domain wall below the tetragonal-orthorhombic phase transition in BaTiO3

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F25%3A00604068" target="_blank" >RIV/68378271:_____/25:00604068 - isvavai.cz</a>

Výsledek na webu

<a href="https://hdl.handle.net/11104/0361402" target="_blank" >https://hdl.handle.net/11104/0361402</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1063/5.0247479" target="_blank" >10.1063/5.0247479</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Fragmented charged domain wall below the tetragonal-orthorhombic phase transition in BaTiO3

Popis výsledku v původním jazyce

Ferroelectric charged domain walls are known for their high electrical conductivity, making them promising candidates for modern electronics. A remarkably high conductivity and nominal charge density has been found in the head-to-head ferroelastic domain wall of tetragonal barium titanate. Conductivity of this domain wall decreases by several orders of magnitude when the temperature drops down below about 5 °C when the tetragonal phase transforms to the orthorhombic one. We explored the evolution of these ferroelectric charged domain walls in BaTiO3 crystals, while they undergo this phase transition by in situ optical microscopy. Our results reveal that, below the phase transition, the domains adjacent to charge domain walls become twinned, and the head-to-head charged domain wall transforms into a superdomain wall, which is broken into alternating micrometer-scale segments with and without the excess bound charge. Since the macroscopic conductive channel along such fragmented superdomain wall is disrupted, these observations explain the observed loss of the domain wall conductivity below the phase transition.

Název v anglickém jazyce

Fragmented charged domain wall below the tetragonal-orthorhombic phase transition in BaTiO3

Popis výsledku anglicky

Ferroelectric charged domain walls are known for their high electrical conductivity, making them promising candidates for modern electronics. A remarkably high conductivity and nominal charge density has been found in the head-to-head ferroelastic domain wall of tetragonal barium titanate. Conductivity of this domain wall decreases by several orders of magnitude when the temperature drops down below about 5 °C when the tetragonal phase transforms to the orthorhombic one. We explored the evolution of these ferroelectric charged domain walls in BaTiO3 crystals, while they undergo this phase transition by in situ optical microscopy. Our results reveal that, below the phase transition, the domains adjacent to charge domain walls become twinned, and the head-to-head charged domain wall transforms into a superdomain wall, which is broken into alternating micrometer-scale segments with and without the excess bound charge. Since the macroscopic conductive channel along such fragmented superdomain wall is disrupted, these observations explain the observed loss of the domain wall conductivity below the phase transition.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2025

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Applied Physics Letters

ISSN

0003-6951

e-ISSN

1077-3118

Svazek periodika

126

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

5

Strana od-do

012909

Kód UT WoS článku

001392786000003

EID výsledku v databázi Scopus

2-s2.0-85214647190