Iron(II) and iron(III) complexes with sulphate anion or ligand, their thermal behaviour and magnetic properties

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F25%3A00640574" target="_blank" >RIV/68378271:_____/25:00640574 - isvavai.cz</a>

Výsledek na webu

<a href="https://hdl.handle.net/11104/0370960" target="_blank" >https://hdl.handle.net/11104/0370960</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s11243-025-00674-2" target="_blank" >10.1007/s11243-025-00674-2</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Iron(II) and iron(III) complexes with sulphate anion or ligand, their thermal behaviour and magnetic properties

Popis výsledku v původním jazyce

Reactions of ferrous or ferric sulphates with the chelating diamine ligands bpy (2,2'-bipyridine) and phen (1,10-phenanthroline) in methanol/water solution yielded two new complexes, a green FeIII complex [Fe2(bpy)2(H2O)2O(SO4)2]·3H2O 1 and dark red complex [Fe(phen)3](SO4)·8.4H2O 2. Both complexes were characterized using chemical and spectroscopic methods (IR, UV–Vis). Single-crystal X-ray study showed that 1 exhibits molecular structure formed of dinuclear complex molecules comprising {Fe–O–Fe} structural unit with close distance between the deformed octahedrally coordinated Fe atoms (3.1857(8) Å) and the unit cell content is completed by water solvate molecules. The crystal structure of 2 is ionic and is formed of [Fe(phen)3]2+ complex cation, sulphate anion and water solvate molecules.n

Název v anglickém jazyce

Iron(II) and iron(III) complexes with sulphate anion or ligand, their thermal behaviour and magnetic properties

Popis výsledku anglicky

Reactions of ferrous or ferric sulphates with the chelating diamine ligands bpy (2,2'-bipyridine) and phen (1,10-phenanthroline) in methanol/water solution yielded two new complexes, a green FeIII complex [Fe2(bpy)2(H2O)2O(SO4)2]·3H2O 1 and dark red complex [Fe(phen)3](SO4)·8.4H2O 2. Both complexes were characterized using chemical and spectroscopic methods (IR, UV–Vis). Single-crystal X-ray study showed that 1 exhibits molecular structure formed of dinuclear complex molecules comprising {Fe–O–Fe} structural unit with close distance between the deformed octahedrally coordinated Fe atoms (3.1857(8) Å) and the unit cell content is completed by water solvate molecules. The crystal structure of 2 is ionic and is formed of [Fe(phen)3]2+ complex cation, sulphate anion and water solvate molecules.n

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Projekt

<a href="/cs/project/EH22_008%2F0004594" target="_blank" >EH22_008/0004594: Teraferoika pro ultravysokou kapacitu, rychlost a energetickou úspornost informačních technologií</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2025

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Transition Metal Chemistry

ISSN

0340-4285

e-ISSN

1572-901X

Svazek periodika

50

Číslo periodika v rámci svazku

Dec

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

20

Strana od-do

1013-1032

Kód UT WoS článku

001538542700001

EID výsledku v databázi Scopus

2-s2.0-105012184717