Tb3+ and Ce3+ as a functional couple for enhanced luminescence in YAG ceramics for X-ray imaging and high-power white LEDs and laser diodes

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F25%3A00641700" target="_blank" >RIV/68378271:_____/25:00641700 - isvavai.cz</a>

Výsledek na webu

<a href="https://hdl.handle.net/11104/0372128" target="_blank" >https://hdl.handle.net/11104/0372128</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/d5ma00464k" target="_blank" >10.1039/d5ma00464k</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Tb3+ and Ce3+ as a functional couple for enhanced luminescence in YAG ceramics for X-ray imaging and high-power white LEDs and laser diodes

Popis výsledku v původním jazyce

The exposure of luminescent materials to X-ray radiation and high-power laser excitation results in significant heating, leading to thermal quenching and a corresponding reduction in phosphor efficiency. This study aimed to address this limitation by enhancing material efficiency while maintaining high thermal stability. YAG:Ce,Tb transparent ceramics were successfully fabricated via vacuum reactive sintering method, with moderate concentrations of Tb3+ ions (1, 5 and 10 at%) codopants. These ceramics exhibited a dense microstructure without micropores, achieving high transparency of 77–80% at 900 nm. The incorporation of Tb3+ ions, is evidenced by the systematic increase in lattice constants from 12.608 Å (YAG:Ce) to 12.615 Å (YAG:Ce,Tb10%) in accordance with Vegard's law. The phonon-assisted Ce3+ ↔ Tb3+ bidirectional resonance mechanism, which facilitated energy transfer between Ce3+ and Tb3+ ions, was observed. The optimal transfer rate was observed at approximately 480 K. Beyond this temperature, the rate progressively accelerated, leading to accelerated decay times. Notably, YAG:Ce,Tb10% ceramics demonstrated a two-fold increase in radioluminescence intensity compared to uncodoped YAG:Ce ceramics. This substantial improvement in luminescence performance highlights the potential of YAG:Ce,Tb ceramics as highly efficient phosphors for X-ray imaging applications, offering enhanced brightness and energy transfer efficiency under high-temperature operating conditions. The Tb3+ codoping also enhanced Ce3+ emission, allowing for tuning of the correlated color temperature to a maximum of 6013 K, while maintaining a stable color rendering index of 69–73 and luminous efficacy of ∼123 lm W−1. It was shown that the luminous efficacy was not a constant parameter, but depended on the excitation laser power, initially increasing with power up to 0.5 W and then saturating. These results establish YAG:Ce,Tb transparent ceramics as highly promising materials for white LEDs due to their good thermal stability, tunable optical properties, and enhanced luminescence performance.n

Název v anglickém jazyce

Tb3+ and Ce3+ as a functional couple for enhanced luminescence in YAG ceramics for X-ray imaging and high-power white LEDs and laser diodes

Popis výsledku anglicky

The exposure of luminescent materials to X-ray radiation and high-power laser excitation results in significant heating, leading to thermal quenching and a corresponding reduction in phosphor efficiency. This study aimed to address this limitation by enhancing material efficiency while maintaining high thermal stability. YAG:Ce,Tb transparent ceramics were successfully fabricated via vacuum reactive sintering method, with moderate concentrations of Tb3+ ions (1, 5 and 10 at%) codopants. These ceramics exhibited a dense microstructure without micropores, achieving high transparency of 77–80% at 900 nm. The incorporation of Tb3+ ions, is evidenced by the systematic increase in lattice constants from 12.608 Å (YAG:Ce) to 12.615 Å (YAG:Ce,Tb10%) in accordance with Vegard's law. The phonon-assisted Ce3+ ↔ Tb3+ bidirectional resonance mechanism, which facilitated energy transfer between Ce3+ and Tb3+ ions, was observed. The optimal transfer rate was observed at approximately 480 K. Beyond this temperature, the rate progressively accelerated, leading to accelerated decay times. Notably, YAG:Ce,Tb10% ceramics demonstrated a two-fold increase in radioluminescence intensity compared to uncodoped YAG:Ce ceramics. This substantial improvement in luminescence performance highlights the potential of YAG:Ce,Tb ceramics as highly efficient phosphors for X-ray imaging applications, offering enhanced brightness and energy transfer efficiency under high-temperature operating conditions. The Tb3+ codoping also enhanced Ce3+ emission, allowing for tuning of the correlated color temperature to a maximum of 6013 K, while maintaining a stable color rendering index of 69–73 and luminous efficacy of ∼123 lm W−1. It was shown that the luminous efficacy was not a constant parameter, but depended on the excitation laser power, initially increasing with power up to 0.5 W and then saturating. These results establish YAG:Ce,Tb transparent ceramics as highly promising materials for white LEDs due to their good thermal stability, tunable optical properties, and enhanced luminescence performance.n

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10306 - Optics (including laser optics and quantum optics)

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2025

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Materials Advances

ISSN

2633-5409

e-ISSN

2633-5409

Svazek periodika

6

Číslo periodika v rámci svazku

22

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

15

Strana od-do

8464-8478

Kód UT WoS článku

001593356700001

EID výsledku v databázi Scopus

2-s2.0-105025966463