Deterioration of basalt-based reinforcement in corrosive environments: Experimental monitoring and mathematical models

Kód výsledku v IS VaVaI

RIV/68407700:21110/23:00370808 - isvavai.cz

Výsledek na webu

http://dx.doi.org/10.1088/1742-6596/2628/1/012012

DOI - Digital Object Identifier

10.1088/1742-6596/2628/1/012012

Jazyk výsledku

angličtina

Název v původním jazyce

Deterioration of basalt-based reinforcement in corrosive environments: Experimental monitoring and mathematical models

Popis výsledku v původním jazyce

The basalt-based reinforcing elements are considered as alternative to conventional steel-based reinforcing elements (rebars, wires). The motivation to use basalt-based elements (fibers, composite bars, meshes etc.) is better corrosion resistance of basalt fibers especially in sea-water environment, compared to carbon steel. Nevertheless, it does not mean that basalt fibers are 100% corrosion resistant. The basalt fibers are produced from silicate melt of proper composition, i.e. the basalt fibers are vulnerable to both acid and alkaline hydrolysis, as well as other silicates do. When basalt fibers are used as reinforcement in concrete, the alkaline hydrolysis will become an important issue. The present paper deals with experimental observation of basalt fibers in alkaline environment of Simulated Pore Solution. The fibers deterioration was monitored by their mass loss and SEM microscopy. Jander's model was used to describe mathematically the kinetics of the fibers alkaline hydrolysis. The results revealed that a corrosion products layer is formed on the fibers surface in this environment. The composition of this layer corresponds to N-A-S-H and C-A-S-H phases known from alkali-activated aluminosilicates or hydrated Portland cement.

Název v anglickém jazyce

Deterioration of basalt-based reinforcement in corrosive environments: Experimental monitoring and mathematical models

Popis výsledku anglicky

The basalt-based reinforcing elements are considered as alternative to conventional steel-based reinforcing elements (rebars, wires). The motivation to use basalt-based elements (fibers, composite bars, meshes etc.) is better corrosion resistance of basalt fibers especially in sea-water environment, compared to carbon steel. Nevertheless, it does not mean that basalt fibers are 100% corrosion resistant. The basalt fibers are produced from silicate melt of proper composition, i.e. the basalt fibers are vulnerable to both acid and alkaline hydrolysis, as well as other silicates do. When basalt fibers are used as reinforcement in concrete, the alkaline hydrolysis will become an important issue. The present paper deals with experimental observation of basalt fibers in alkaline environment of Simulated Pore Solution. The fibers deterioration was monitored by their mass loss and SEM microscopy. Jander's model was used to describe mathematically the kinetics of the fibers alkaline hydrolysis. The results revealed that a corrosion products layer is formed on the fibers surface in this environment. The composition of this layer corresponds to N-A-S-H and C-A-S-H phases known from alkali-activated aluminosilicates or hydrated Portland cement.

Druh

D - Stať ve sborníku

CEP obor

—

OECD FORD obor

20505 - Composites (including laminates, reinforced plastics, cermets, combined natural and synthetic fibre fabrics; filled composites)

Projekt

GA21-00800S: Chemické a fyzikální interakce výztuže na čedičové bázi s cementovou matricí

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název statě ve sborníku

Journal of Physics: Conference Series 2628 (2023)

ISBN

—

ISSN

1742-6588

e-ISSN

1742-6596

Počet stran výsledku

5

Strana od-do

—

Název nakladatele

IOP Publishing Ltd.

Místo vydání

Bristol

Místo konání akce

Poprad

Datum konání akce

6. 9. 2023

Typ akce podle státní příslušnosti

WRD - Celosvětová akce

Kód UT WoS článku

—