Dry additive desulfurization in oxyfuel bubbling fluidized bed combustor

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21220%2F21%3A00346820" target="_blank" >RIV/68407700:21220/21:00346820 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.1016/j.fuel.2020.118945" target="_blank" >https://doi.org/10.1016/j.fuel.2020.118945</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.fuel.2020.118945" target="_blank" >10.1016/j.fuel.2020.118945</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Dry additive desulfurization in oxyfuel bubbling fluidized bed combustor

Popis výsledku v původním jazyce

This work presents research results of direct sorbent addition for SO2 capture from a lignite coal combustion in a bubbling fluidized bed (BFB). SO2 capture ratio in air and in full oxyfuel combustion conditions is compared in real environment, using a 30 kW BFB combustor. The first part studies the sulfur self-retention in the fuel ash. It shows significantly more efficient SO2 capture increase from 15% in air conditions to 45% in oxyfuel conditions. The next part concerns evaluation of optimal temperature for the SO2 capture and a sorbent performance is evaluated in the last part. Two varieties of sorbents based on CaCO3 were used, differing significantly in purity, geological age and BET surface area. The optimal fluidized bed temperature for SO2 capture was for air combustion about 840 degrees C and for oxyfuel combustion about 880 degrees C. The sorbent performance was studied at three different Ca/S molar ratios (1.5, 3 and 5). The results show the fundamental differences between air and oxyfuel conditions in real combustion environment, and also reveal the differences between the sorbents. In general, significantly higher SO2 capture ratio was reached in oxyfuel conditions. At Ca/S equal to 5, it is possible to reach the SO2 capture as high as 98% in oxyfuel mode. The BET surface of the sorbent is important mainly at lower Ca/S molar ratios. The difference in SO2 capture between the sorbents is below 10% relative at Ca/S molar ratio 3 and it further decreases with increasing Ca/S ratio.

Název v anglickém jazyce

Dry additive desulfurization in oxyfuel bubbling fluidized bed combustor

Popis výsledku anglicky

This work presents research results of direct sorbent addition for SO2 capture from a lignite coal combustion in a bubbling fluidized bed (BFB). SO2 capture ratio in air and in full oxyfuel combustion conditions is compared in real environment, using a 30 kW BFB combustor. The first part studies the sulfur self-retention in the fuel ash. It shows significantly more efficient SO2 capture increase from 15% in air conditions to 45% in oxyfuel conditions. The next part concerns evaluation of optimal temperature for the SO2 capture and a sorbent performance is evaluated in the last part. Two varieties of sorbents based on CaCO3 were used, differing significantly in purity, geological age and BET surface area. The optimal fluidized bed temperature for SO2 capture was for air combustion about 840 degrees C and for oxyfuel combustion about 880 degrees C. The sorbent performance was studied at three different Ca/S molar ratios (1.5, 3 and 5). The results show the fundamental differences between air and oxyfuel conditions in real combustion environment, and also reveal the differences between the sorbents. In general, significantly higher SO2 capture ratio was reached in oxyfuel conditions. At Ca/S equal to 5, it is possible to reach the SO2 capture as high as 98% in oxyfuel mode. The BET surface of the sorbent is important mainly at lower Ca/S molar ratios. The difference in SO2 capture between the sorbents is below 10% relative at Ca/S molar ratio 3 and it further decreases with increasing Ca/S ratio.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20704 - Energy and fuels

Projekt

<a href="/cs/project/EF16_019%2F0000753" target="_blank" >EF16_019/0000753: Centrum výzkumu nízkouhlíkových energetických technologií</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Fuel

ISSN

0016-2361

e-ISSN

1873-7153

Svazek periodika

283

Číslo periodika v rámci svazku

118945

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

9

Strana od-do

—

Kód UT WoS článku

000584919700107

EID výsledku v databázi Scopus

2-s2.0-85089516280