Toughening mechanisms in V-Si-N coatings

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21230%2F21%3A00351651" target="_blank" >RIV/68407700:21230/21:00351651 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.1016/j.matdes.2021.109961" target="_blank" >https://doi.org/10.1016/j.matdes.2021.109961</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.matdes.2021.109961" target="_blank" >10.1016/j.matdes.2021.109961</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Toughening mechanisms in V-Si-N coatings

Popis výsledku v původním jazyce

Microstructural evolution and deformation mechanisms of magnetron sputtered V-Si-N coatings with various Si contents are investigated by transmission electron microscopy, X-ray absorption spectroscopy, and ab initio calculations. A small amount of Si atoms was dissolved into the cubic VN lattice, locally reducing the neighboring V-N p-d hybridization near the Si site. The Si content was found to impact the architecture of coating significantly. With increasing Si content, the microstructure evolved through three different architectures: (i) highly textured columnar grains, (ii) refined columnar grains, and (iii) nanocomposite structures where elongated grains were bounded by vein-like boundaries. Enhanced damage tolerance was observed in the nanocomposite structure, where multiple toughening mechanisms become active. Ab initio calculations revealed that the incorporation of Si monolayer in the (111) -oriented VN resulted in the formation of weaker Si-N bonds compared to V-N bonds, which allowed a selective response to strain and shear deformations by assisting the activation of the slip systems. (c) 2021 Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http:// creativecommons.org/licenses/by-nc-nd/4.0/).

Název v anglickém jazyce

Toughening mechanisms in V-Si-N coatings

Popis výsledku anglicky

Microstructural evolution and deformation mechanisms of magnetron sputtered V-Si-N coatings with various Si contents are investigated by transmission electron microscopy, X-ray absorption spectroscopy, and ab initio calculations. A small amount of Si atoms was dissolved into the cubic VN lattice, locally reducing the neighboring V-N p-d hybridization near the Si site. The Si content was found to impact the architecture of coating significantly. With increasing Si content, the microstructure evolved through three different architectures: (i) highly textured columnar grains, (ii) refined columnar grains, and (iii) nanocomposite structures where elongated grains were bounded by vein-like boundaries. Enhanced damage tolerance was observed in the nanocomposite structure, where multiple toughening mechanisms become active. Ab initio calculations revealed that the incorporation of Si monolayer in the (111) -oriented VN resulted in the formation of weaker Si-N bonds compared to V-N bonds, which allowed a selective response to strain and shear deformations by assisting the activation of the slip systems. (c) 2021 Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http:// creativecommons.org/licenses/by-nc-nd/4.0/).

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20506 - Coating and films

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Materials & Design

ISSN

0264-1275

e-ISSN

1873-4197

Svazek periodika

209

Číslo periodika v rámci svazku

November

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

13

Strana od-do

—

Kód UT WoS článku

000697464100002

EID výsledku v databázi Scopus

2-s2.0-85109779914