Separation of the Minor Actinides Americium(III) and Curium(III) by Hydrophobic and Hydrophilic BTPhen Ligands: Exploiting Differences in their Rates of Extraction and Effective Separations at Equilibrium

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21340%2F18%3A00321447" target="_blank" >RIV/68407700:21340/18:00321447 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1080/07366299.2018.1429358" target="_blank" >http://dx.doi.org/10.1080/07366299.2018.1429358</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1080/07366299.2018.1429358" target="_blank" >10.1080/07366299.2018.1429358</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Separation of the Minor Actinides Americium(III) and Curium(III) by Hydrophobic and Hydrophilic BTPhen Ligands: Exploiting Differences in their Rates of Extraction and Effective Separations at Equilibrium

Popis výsledku v původním jazyce

The complexation and extraction of the adjacent minor actinides Am(III) and Cm(III) by both hydrophobic and hydrophilic pre-organized 2,9-bis(1,2,4-triazin-3-yl)-1,10-phenanthroline (BTPhen) ligands has been studied in detail. It has been shown that Am(III) is extracted more rapidly than Cm(III) by the hydrophobic CyMe4-BTPhen ligand into different organic diluents under non-equilibrium extraction conditions, leading to separation factors for Am over Cm (SFAm/Cm) as high as 7.9. Furthermore, the selectivity for Am(III) over Cm(III) can be tuned through careful choice of the extraction conditions (organic diluent, contact time, mixing speed, ligand concentration). This `kinetic’ effect is attributed to the higher presumed kinetic lability of the Am(III) aqua complex towards ligand substitution. A dependence of the Am(III)/Cm(III) selectivity on the structure of the alkyl groups attached to the triazine rings is also observed, and BTPhens bearing linear alkyl groups are less able to discriminate between Am(III) and Cm(III) than CyMe4-BTPhen. Under equilibrium extraction conditions, hydrophilic tetrasulfonated BTPhen ligands complex selectively Am(III) over Cm(III) and prevent the extraction of Am(III) from nitric acid by the hydrophobic O-donor ligand N,N,N’,N’-tetraoctyldiglycolamide (TODGA), giving separation factors for Cm(III) over Am(III) (SFCm/Am) of up to 4.6. These results further underline the utility of the BTPhen ligands for the challenging separation of the chemically similar minor actinides Am(III) and Cm(III).

Název v anglickém jazyce

Separation of the Minor Actinides Americium(III) and Curium(III) by Hydrophobic and Hydrophilic BTPhen Ligands: Exploiting Differences in their Rates of Extraction and Effective Separations at Equilibrium

Popis výsledku anglicky

The complexation and extraction of the adjacent minor actinides Am(III) and Cm(III) by both hydrophobic and hydrophilic pre-organized 2,9-bis(1,2,4-triazin-3-yl)-1,10-phenanthroline (BTPhen) ligands has been studied in detail. It has been shown that Am(III) is extracted more rapidly than Cm(III) by the hydrophobic CyMe4-BTPhen ligand into different organic diluents under non-equilibrium extraction conditions, leading to separation factors for Am over Cm (SFAm/Cm) as high as 7.9. Furthermore, the selectivity for Am(III) over Cm(III) can be tuned through careful choice of the extraction conditions (organic diluent, contact time, mixing speed, ligand concentration). This `kinetic’ effect is attributed to the higher presumed kinetic lability of the Am(III) aqua complex towards ligand substitution. A dependence of the Am(III)/Cm(III) selectivity on the structure of the alkyl groups attached to the triazine rings is also observed, and BTPhens bearing linear alkyl groups are less able to discriminate between Am(III) and Cm(III) than CyMe4-BTPhen. Under equilibrium extraction conditions, hydrophilic tetrasulfonated BTPhen ligands complex selectively Am(III) over Cm(III) and prevent the extraction of Am(III) from nitric acid by the hydrophobic O-donor ligand N,N,N’,N’-tetraoctyldiglycolamide (TODGA), giving separation factors for Cm(III) over Am(III) (SFCm/Am) of up to 4.6. These results further underline the utility of the BTPhen ligands for the challenging separation of the chemically similar minor actinides Am(III) and Cm(III).

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10400 - Chemical sciences

Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2018

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Solvent Extraction and Ion Exchange

ISSN

0736-6299

e-ISSN

1532-2262

Svazek periodika

36

Číslo periodika v rámci svazku

2

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

21

Strana od-do

115-135

Kód UT WoS článku

000430081400001

EID výsledku v databázi Scopus

2-s2.0-85040996866