Surface Complexation Models of Pertechnetate on Biochar/Montmorillonite Composite—Batch and Dynamic Sorption Study

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21340%2F20%3A00342751" target="_blank" >RIV/68407700:21340/20:00342751 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.3390/ma13143108" target="_blank" >https://doi.org/10.3390/ma13143108</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/ma13143108" target="_blank" >10.3390/ma13143108</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Surface Complexation Models of Pertechnetate on Biochar/Montmorillonite Composite—Batch and Dynamic Sorption Study

Popis výsledku v původním jazyce

The study summarizes the results of monitoring the properties of two types of sorbents, BC1 (biochar sample 1) and BC2a (biochar sample 2), prepared by pyrolysis of bamboo biomass (BC1) and as its composite with montmorillonite K10 (BC2a). The main goal was to study their applicability to the Tc (VII) separation from liquid wastes, using NH4ReO4 as a carrier. The research was focused on determining the sorbents surface properties (by XRF (X-ray fluorescence) method and potentiometric titration in order to determine the properties of surface groups—Chemical Equilibrium Model (CEM) and Ion Exchange Model (IExM) models were applied here). As well as monitoring Tc (VII) (+Re(VII)) sorption, especially to determine equilibrium isotherm, the influence of pH and kinetics. The subject of research was also the dynamics of sorption, including its mathematical–physical modeling. Both sorbents have good properties against Tc (VII), however BC2a, due to the presence of montmorillonite, is more advantageous in this respect. It has a higher sorption capacity and faster kinetic investigation. An important finding is that the optimal pH is 2–3, which is related not only to the protonation of surface groups (they have a positive charge), but also to the negative form of the existence of Tc (VII) and Re (VII): TcO4- and ReO4-.

Název v anglickém jazyce

Surface Complexation Models of Pertechnetate on Biochar/Montmorillonite Composite—Batch and Dynamic Sorption Study

Popis výsledku anglicky

The study summarizes the results of monitoring the properties of two types of sorbents, BC1 (biochar sample 1) and BC2a (biochar sample 2), prepared by pyrolysis of bamboo biomass (BC1) and as its composite with montmorillonite K10 (BC2a). The main goal was to study their applicability to the Tc (VII) separation from liquid wastes, using NH4ReO4 as a carrier. The research was focused on determining the sorbents surface properties (by XRF (X-ray fluorescence) method and potentiometric titration in order to determine the properties of surface groups—Chemical Equilibrium Model (CEM) and Ion Exchange Model (IExM) models were applied here). As well as monitoring Tc (VII) (+Re(VII)) sorption, especially to determine equilibrium isotherm, the influence of pH and kinetics. The subject of research was also the dynamics of sorption, including its mathematical–physical modeling. Both sorbents have good properties against Tc (VII), however BC2a, due to the presence of montmorillonite, is more advantageous in this respect. It has a higher sorption capacity and faster kinetic investigation. An important finding is that the optimal pH is 2–3, which is related not only to the protonation of surface groups (they have a positive charge), but also to the negative form of the existence of Tc (VII) and Re (VII): TcO4- and ReO4-.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10400 - Chemical sciences

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Materials

ISSN

1996-1944

e-ISSN

1996-1944

Svazek periodika

13

Číslo periodika v rámci svazku

14

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

17

Strana od-do

1-17

Kód UT WoS článku

000558282500001

EID výsledku v databázi Scopus

2-s2.0-85088498176