1D Coordination pi-d Conjugated Polymers with Distinct Structures Defined by the Choice of the Transition Metal: Towards a New Class of Antiaromatic Macrocycles

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21340%2F21%3A00349574" target="_blank" >RIV/68407700:21340/21:00349574 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61989592:15310/20:73604263

Výsledek na webu

<a href="https://doi.org/10.1002/anie.202011462" target="_blank" >https://doi.org/10.1002/anie.202011462</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/anie.202011462" target="_blank" >10.1002/anie.202011462</a>

Jazyk výsledku

angličtina

Název v původním jazyce

1D Coordination pi-d Conjugated Polymers with Distinct Structures Defined by the Choice of the Transition Metal: Towards a New Class of Antiaromatic Macrocycles

Popis výsledku v původním jazyce

Recently pi-d conjugated coordination polymers have received a lot of attention owing to their unique material properties, although synthesis of long and defect-free polymers remains challenging. Herein we introduce a novel on-surface synthesis of coordination polymers with quinoidal ligands under ultra-high vacuum conditions, which enables formation of flexible coordination polymers with lengths up to hundreds of nanometers. Moreover, this procedure allows the incorporation of different transition-metal atoms with four- or two-fold coordination. Remarkably, the two-fold coordination mode revealed the formation of wires constituted by (electronically) independent 12-membered antiaromatic macrocycles linked together through two C-C single bonds.

Název v anglickém jazyce

1D Coordination pi-d Conjugated Polymers with Distinct Structures Defined by the Choice of the Transition Metal: Towards a New Class of Antiaromatic Macrocycles

Popis výsledku anglicky

Recently pi-d conjugated coordination polymers have received a lot of attention owing to their unique material properties, although synthesis of long and defect-free polymers remains challenging. Herein we introduce a novel on-surface synthesis of coordination polymers with quinoidal ligands under ultra-high vacuum conditions, which enables formation of flexible coordination polymers with lengths up to hundreds of nanometers. Moreover, this procedure allows the incorporation of different transition-metal atoms with four- or two-fold coordination. Remarkably, the two-fold coordination mode revealed the formation of wires constituted by (electronically) independent 12-membered antiaromatic macrocycles linked together through two C-C single bonds.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

21002 - Nano-processes (applications on nano-scale); (biomaterials to be 2.9)

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Angewandte Chemie International Edition

ISSN

1433-7851

e-ISSN

1521-3773

Svazek periodika

60

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

7

Strana od-do

439-445

Kód UT WoS článku

000584114800001

EID výsledku v databázi Scopus

2-s2.0-85096679868