Enhancement Of Molecular Weight Of L-Lactic Acid Polycondensates Under Vacuum In Solid State

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28110%2F12%3A43868024" target="_blank" >RIV/70883521:28110/12:43868024 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/70883521:28610/12:43868024

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Enhancement Of Molecular Weight Of L-Lactic Acid Polycondensates Under Vacuum In Solid State

Popis výsledku v původním jazyce

Enhancement of L-lactic acid polycondensates by involving of postpolycondensation reactions in solid state under vacuum and catalyzed by stannous 2-ethylhexanoate were studied in the presented work. The catalyst was used only in postpolycondensation step. An effect of the catalyst concentration and postpolycondensation reaction time on resulting properties of poly(lactic acid) was studied by gel permeation chromatography. Fourier transform infrared spectroscopy and differential scanning calorimetry. Results show significant enhancement of molecular weight in case of the systems containing 2 wt. % of the catalyst due to the postpolycondensation procedure (M-W similar to 91.0 kg/mol; i.e. 1655 % after 24 hours). However, further progress can be assumed with increasing reaction time. This enhancement of poly(lactic acid) molecular weight had a response corresponding to changes of both physico-chemical and thermal properties of the solid state postpolycondensation products.

Název v anglickém jazyce

Enhancement Of Molecular Weight Of L-Lactic Acid Polycondensates Under Vacuum In Solid State

Popis výsledku anglicky

Enhancement of L-lactic acid polycondensates by involving of postpolycondensation reactions in solid state under vacuum and catalyzed by stannous 2-ethylhexanoate were studied in the presented work. The catalyst was used only in postpolycondensation step. An effect of the catalyst concentration and postpolycondensation reaction time on resulting properties of poly(lactic acid) was studied by gel permeation chromatography. Fourier transform infrared spectroscopy and differential scanning calorimetry. Results show significant enhancement of molecular weight in case of the systems containing 2 wt. % of the catalyst due to the postpolycondensation procedure (M-W similar to 91.0 kg/mol; i.e. 1655 % after 24 hours). However, further progress can be assumed with increasing reaction time. This enhancement of poly(lactic acid) molecular weight had a response corresponding to changes of both physico-chemical and thermal properties of the solid state postpolycondensation products.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CD - Makromolekulární chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2012

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Materiali in Tehnologije

ISSN

1580-2949

e-ISSN

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Svazek periodika

46

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

SI - Slovinská republika

Počet stran výsledku

5

Strana od-do

37-41

Kód UT WoS článku

000300600100007

EID výsledku v databázi Scopus

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