A self-healable and easily recyclable supramolecular hydrogel electrolyte for flexible supercapacitors

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28610%2F16%3A43874451" target="_blank" >RIV/70883521:28610/16:43874451 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1039/c6ta01441k" target="_blank" >http://dx.doi.org/10.1039/c6ta01441k</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/c6ta01441k" target="_blank" >10.1039/c6ta01441k</a>

Jazyk výsledku

angličtina

Název v původním jazyce

A self-healable and easily recyclable supramolecular hydrogel electrolyte for flexible supercapacitors

Popis výsledku v původním jazyce

Although research on polymer hydrogel electrolytes has achieved great progress, their practical application is restricted due to their vulnerability and non-recyclability problems caused by covalent cross-linking effects. Herein, we report a ferric ion cross-linked supramolecular PAA hydrogel electrolyte (KCl-Fe3+/PAA), in which the ionic bond and hydrogen bond endow the KCl-Fe3+/PAA hydrogel electrolyte with favorable self-healing ability and easy-recyclability. In addition, considering the eco-friendly and cost effective properties of both ferric ion and polyacrylic acid, there would be great potential for this KCl-Fe3+/PAA hydrogel electrolyte to be broadly applied. Meanwhile, the hydrogel electrolyte maintained good mechanical performance (extensibility > 700%, and stress > 400 kPa) and excellent conductivity (0.09 S cm-1), which completely satisfy the demands of flexible supercapacitors. After being assembled with graphene foam supported polypyrrole electrodes, the electrochemical performance of this flexible supercapacitor is comparable to that of its liquid electrolyte counterpart.

Název v anglickém jazyce

A self-healable and easily recyclable supramolecular hydrogel electrolyte for flexible supercapacitors

Popis výsledku anglicky

Although research on polymer hydrogel electrolytes has achieved great progress, their practical application is restricted due to their vulnerability and non-recyclability problems caused by covalent cross-linking effects. Herein, we report a ferric ion cross-linked supramolecular PAA hydrogel electrolyte (KCl-Fe3+/PAA), in which the ionic bond and hydrogen bond endow the KCl-Fe3+/PAA hydrogel electrolyte with favorable self-healing ability and easy-recyclability. In addition, considering the eco-friendly and cost effective properties of both ferric ion and polyacrylic acid, there would be great potential for this KCl-Fe3+/PAA hydrogel electrolyte to be broadly applied. Meanwhile, the hydrogel electrolyte maintained good mechanical performance (extensibility > 700%, and stress > 400 kPa) and excellent conductivity (0.09 S cm-1), which completely satisfy the demands of flexible supercapacitors. After being assembled with graphene foam supported polypyrrole electrodes, the electrochemical performance of this flexible supercapacitor is comparable to that of its liquid electrolyte counterpart.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

JE - Nejaderná energetika, spotřeba a užití energie

OECD FORD obor

—

Projekt

—

Návaznosti

N - Vyzkumna aktivita podporovana z neverejnych zdroju

Rok uplatnění

2016

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Materials Chemistry A

ISSN

2050-7488

e-ISSN

—

Svazek periodika

4

Číslo periodika v rámci svazku

22

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

8

Strana od-do

8769-8776

Kód UT WoS článku

000378583200032

EID výsledku v databázi Scopus

2-s2.0-84973344372