Carbodiimide additive to control hydrolytic stability and biodegradability of PLA

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28610%2F16%3A43874571" target="_blank" >RIV/70883521:28610/16:43874571 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/70883521:28110/16:43874571

Výsledek na webu

<a href="http://www.sciencedirect.com/science/article/pii/S0142941816302446" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0142941816302446</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.polymertesting.2016.06.007" target="_blank" >10.1016/j.polymertesting.2016.06.007</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Carbodiimide additive to control hydrolytic stability and biodegradability of PLA

Popis výsledku v původním jazyce

Enhanced durability of bio-based polylactic acid (PLA) is one of the prerequisites to be a considered as alternative to petroleum-based polymers in long time application. The effect of bis(2,6-diisopropylphenyl)carbodiimide (BDICDI) additive in various concentration on the extent of hydrolytic stabilization and subsequent degradation kinetics of PLA was studied in the process of abiotic hydrolysis and microbial decomposition under composting conditions. The study showed that BDICDI acts as an efficient stabilizer suppressing the hydrolytic scission of ester bonds of PLA in both degradation processes tested, especially at concentrations above 1.5% w/w. Within the stabilization period which strongly depends on concentrations of BDICDI, suppression of hydrolytic degradation also triggered preservation of thermal and mechanical properties. After the period of stabilization as the dose of stabilizer is depleted, probably via reaction with water molecules and carboxylic groups, the material was hydrolyzed at a comparable or even slightly higher rate than pure PLA. By applying the appropriate amount of BDICDI, the approximate duration of stabilization could be set to suit the desired requirements of the final product.

Název v anglickém jazyce

Carbodiimide additive to control hydrolytic stability and biodegradability of PLA

Popis výsledku anglicky

Enhanced durability of bio-based polylactic acid (PLA) is one of the prerequisites to be a considered as alternative to petroleum-based polymers in long time application. The effect of bis(2,6-diisopropylphenyl)carbodiimide (BDICDI) additive in various concentration on the extent of hydrolytic stabilization and subsequent degradation kinetics of PLA was studied in the process of abiotic hydrolysis and microbial decomposition under composting conditions. The study showed that BDICDI acts as an efficient stabilizer suppressing the hydrolytic scission of ester bonds of PLA in both degradation processes tested, especially at concentrations above 1.5% w/w. Within the stabilization period which strongly depends on concentrations of BDICDI, suppression of hydrolytic degradation also triggered preservation of thermal and mechanical properties. After the period of stabilization as the dose of stabilizer is depleted, probably via reaction with water molecules and carboxylic groups, the material was hydrolyzed at a comparable or even slightly higher rate than pure PLA. By applying the appropriate amount of BDICDI, the approximate duration of stabilization could be set to suit the desired requirements of the final product.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CD - Makromolekulární chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2016

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Polymer Testing

ISSN

0142-9418

e-ISSN

—

Svazek periodika

54

Číslo periodika v rámci svazku

Neuveden

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

10

Strana od-do

19-28

Kód UT WoS článku

000382798300004

EID výsledku v databázi Scopus

2-s2.0-84976462977