ABA and BAB Triblock Copolymers Based on 2-Methyl-2-oxazoline and 2-n-Propyl-2-oxazoline: Synthesis and Thermoresponsive Behavior in Water
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28610%2F17%3A63516640" target="_blank" >RIV/70883521:28610/17:63516640 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1002/macp.201700031" target="_blank" >http://dx.doi.org/10.1002/macp.201700031</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/macp.201700031" target="_blank" >10.1002/macp.201700031</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
ABA and BAB Triblock Copolymers Based on 2-Methyl-2-oxazoline and 2-n-Propyl-2-oxazoline: Synthesis and Thermoresponsive Behavior in Water
Popis výsledku v původním jazyce
Inspired by the well-known amphiphilic block copolymer platform known as Pluronics or poloxamers, a small library of ABA and BAB triblock copolymers comprising hydrophilic 2-methyl-2-oxazoline (A) and thermoresponsive 2-n-propyl-2-oxazoline (B) is synthesized. These novel copolymers exhibit temperature-induced self-assembly in aqueous solution. The formation and size of aggregates depend on the polymer structure, temperature, and concentration. The BAB copolymers tend to agglomerate in water, with the cloud point temperature depending on the length of poly(2-n-propyl-2-oxazoline) chain. On the other hand, ABA copolymers form smaller aggregates with hydrodynamic radius from 25 to 150 nm. The dependence of viscosity and viscoelastic properties on the temperature is also studied. While several Pluronic block copolymers are known to form thermoreversible hydrogels in the concentration range 20–30 wt%, thermogelation is not observed for any of the investigated poly(2-oxazoline)s at the investigated temperature range from 10 to 50 °C. (Figure presented.).
Název v anglickém jazyce
ABA and BAB Triblock Copolymers Based on 2-Methyl-2-oxazoline and 2-n-Propyl-2-oxazoline: Synthesis and Thermoresponsive Behavior in Water
Popis výsledku anglicky
Inspired by the well-known amphiphilic block copolymer platform known as Pluronics or poloxamers, a small library of ABA and BAB triblock copolymers comprising hydrophilic 2-methyl-2-oxazoline (A) and thermoresponsive 2-n-propyl-2-oxazoline (B) is synthesized. These novel copolymers exhibit temperature-induced self-assembly in aqueous solution. The formation and size of aggregates depend on the polymer structure, temperature, and concentration. The BAB copolymers tend to agglomerate in water, with the cloud point temperature depending on the length of poly(2-n-propyl-2-oxazoline) chain. On the other hand, ABA copolymers form smaller aggregates with hydrodynamic radius from 25 to 150 nm. The dependence of viscosity and viscoelastic properties on the temperature is also studied. While several Pluronic block copolymers are known to form thermoreversible hydrogels in the concentration range 20–30 wt%, thermogelation is not observed for any of the investigated poly(2-oxazoline)s at the investigated temperature range from 10 to 50 °C. (Figure presented.).
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10404 - Polymer science
Návaznosti výsledku
Projekt
<a href="/cs/project/LO1504" target="_blank" >LO1504: Centrum polymerních systémů plus</a><br>
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Ostatní
Rok uplatnění
2017
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Macromolecular chemistry and Physics
ISSN
1022-1352
e-ISSN
—
Svazek periodika
218
Číslo periodika v rámci svazku
13
Stát vydavatele periodika
DE - Spolková republika Německo
Počet stran výsledku
12
Strana od-do
—
Kód UT WoS článku
000404903000011
EID výsledku v databázi Scopus
2-s2.0-85018806665