A high-resilience and conductive composite binder for lithium-sulfur batteries
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28610%2F20%3A63526225" target="_blank" >RIV/70883521:28610/20:63526225 - isvavai.cz</a>
Výsledek na webu
<a href="https://www.sciencedirect.com/science/article/pii/S1385894720303958" target="_blank" >https://www.sciencedirect.com/science/article/pii/S1385894720303958</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.cej.2020.124404" target="_blank" >10.1016/j.cej.2020.124404</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
A high-resilience and conductive composite binder for lithium-sulfur batteries
Popis výsledku v původním jazyce
Binder is very important for the cycle stability of lithium-sulfur batteries under high sulfur loading. In this paper, we designed and prepared a waterborne polyurethane/polyacrylic acid/graphene (WPU/PAA/GN) multi-functional composite binder. The polyoxyethylene segments in WPU are used to promote the migration of lithium ions and provide high elongation. The introduction of polyacrylic acid (PAA) and graphene forms a double hydrogen bond network through simple in situ blending, which gives the binder higher strength and electronic conductivity. More importantly, the physical crosslinking of PAA and WPU can achieve high resilience and ensure the integrity of the cathode structure during charging and discharging. In addition, abundant polar functional groups provide strong chemical adsorption for lithium polysulfide. The synergistic effect of various components makes the binder possess the functions of high resilience, good electrical conductivity, and strong adsorption, which provides a simple and effective solution for the practical application of lithium-sulfur batteries. As a result, the assembled lithium-sulfur battery displayed a high initial discharge capacity of 1243 mAh g−1, good cycle stability (81% capacity retention after 500 cycles at 0.5 C) and superior rate performance.
Název v anglickém jazyce
A high-resilience and conductive composite binder for lithium-sulfur batteries
Popis výsledku anglicky
Binder is very important for the cycle stability of lithium-sulfur batteries under high sulfur loading. In this paper, we designed and prepared a waterborne polyurethane/polyacrylic acid/graphene (WPU/PAA/GN) multi-functional composite binder. The polyoxyethylene segments in WPU are used to promote the migration of lithium ions and provide high elongation. The introduction of polyacrylic acid (PAA) and graphene forms a double hydrogen bond network through simple in situ blending, which gives the binder higher strength and electronic conductivity. More importantly, the physical crosslinking of PAA and WPU can achieve high resilience and ensure the integrity of the cathode structure during charging and discharging. In addition, abundant polar functional groups provide strong chemical adsorption for lithium polysulfide. The synergistic effect of various components makes the binder possess the functions of high resilience, good electrical conductivity, and strong adsorption, which provides a simple and effective solution for the practical application of lithium-sulfur batteries. As a result, the assembled lithium-sulfur battery displayed a high initial discharge capacity of 1243 mAh g−1, good cycle stability (81% capacity retention after 500 cycles at 0.5 C) and superior rate performance.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Návaznosti výsledku
Projekt
—
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2020
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Chemical Engineering Journal
ISSN
1385-8947
e-ISSN
—
Svazek periodika
389
Číslo periodika v rámci svazku
Neuveden
Stát vydavatele periodika
NL - Nizozemsko
Počet stran výsledku
9
Strana od-do
—
Kód UT WoS článku
000519528800007
EID výsledku v databázi Scopus
2-s2.0-85079417922