Effect of DMDHEU treatment on properties of bacterial cellulose material

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28610%2F21%3A63528338" target="_blank" >RIV/70883521:28610/21:63528338 - isvavai.cz</a>

Výsledek na webu

<a href="https://journals.sagepub.com/doi/10.1177/0040517521992357" target="_blank" >https://journals.sagepub.com/doi/10.1177/0040517521992357</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1177/0040517521992357" target="_blank" >10.1177/0040517521992357</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Effect of DMDHEU treatment on properties of bacterial cellulose material

Popis výsledku v původním jazyce

The aim of this study was to estimate the influence of purification and treatment with textile finishing agent procedures on structural, mechanical, and water barrier properties of bacterial cellulose (BC) in order to predict the end-use properties. Kombucha fungus generated by Komagataeibacter xylinus species, formerly known as Gluconacetobacter xylinus, was used to produce the BC material. The BC was purified with 0.5% sodium hydroxide (NaOH) solution and treated with 5%, 10%, and 20% concentration of N, N-dimethylol 4,5-dihydroxy-ethylene urea (DMDHEU). By Fourier transform spectroscopy (FTIR) and X-ray diffractometer (XRD) was estimated, that the purification with a weak alkali solution was effective to remove amorphous matter of the BC material. Scanning electron microscope (SEM) images demonstrated the BC structure, similar to a non-woven textile fabric with clearly visible three-dimensional networks of fine cellulose fibers. After the purification process, the BC material tensile strength increased by 52%; however, the strain decreased by 93%. BC material after treatment with 20% DMDHEU regained deformability and tensile properties analogous to untreated samples. Water vapor permeability (WVP) values increased and water absorption capacity (WAC) decreased in BC material with increasing DMDHEU concentration. According to the FTIR results, the crosslinking reaction of DMDHEU and adjacent BC molecules was proved. The treatment with DMDHEU restores the amorphous properties of BC material, and therefore blocks water absorption, and the decrease in the water absorption parameter might be determined.

Název v anglickém jazyce

Effect of DMDHEU treatment on properties of bacterial cellulose material

Popis výsledku anglicky

The aim of this study was to estimate the influence of purification and treatment with textile finishing agent procedures on structural, mechanical, and water barrier properties of bacterial cellulose (BC) in order to predict the end-use properties. Kombucha fungus generated by Komagataeibacter xylinus species, formerly known as Gluconacetobacter xylinus, was used to produce the BC material. The BC was purified with 0.5% sodium hydroxide (NaOH) solution and treated with 5%, 10%, and 20% concentration of N, N-dimethylol 4,5-dihydroxy-ethylene urea (DMDHEU). By Fourier transform spectroscopy (FTIR) and X-ray diffractometer (XRD) was estimated, that the purification with a weak alkali solution was effective to remove amorphous matter of the BC material. Scanning electron microscope (SEM) images demonstrated the BC structure, similar to a non-woven textile fabric with clearly visible three-dimensional networks of fine cellulose fibers. After the purification process, the BC material tensile strength increased by 52%; however, the strain decreased by 93%. BC material after treatment with 20% DMDHEU regained deformability and tensile properties analogous to untreated samples. Water vapor permeability (WVP) values increased and water absorption capacity (WAC) decreased in BC material with increasing DMDHEU concentration. According to the FTIR results, the crosslinking reaction of DMDHEU and adjacent BC molecules was proved. The treatment with DMDHEU restores the amorphous properties of BC material, and therefore blocks water absorption, and the decrease in the water absorption parameter might be determined.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20903 - Bioproducts (products that are manufactured using biological material as feedstock) biomaterials, bioplastics, biofuels, bioderived bulk and fine chemicals, bio-derived novel materials

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Textile Research Journal

ISSN

0040-5175

e-ISSN

—

Svazek periodika

Neuveden

Číslo periodika v rámci svazku

Neuveden

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

11

Strana od-do

—

Kód UT WoS článku

000682125000001

EID výsledku v databázi Scopus

2-s2.0-85100537371