Localization of poly(glycidyl methacrylate) grafted on reduced graphene oxide in poly(lactic acid)/poly(trimethylene terephthalate) blends for composites with enhanced electrical and thermal conductivities
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28610%2F21%3A63544918" target="_blank" >RIV/70883521:28610/21:63544918 - isvavai.cz</a>
Výsledek na webu
<a href="https://pubs.acs.org/doi/10.1021/acsanm.1c01843" target="_blank" >https://pubs.acs.org/doi/10.1021/acsanm.1c01843</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acsanm.1c01843" target="_blank" >10.1021/acsanm.1c01843</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Localization of poly(glycidyl methacrylate) grafted on reduced graphene oxide in poly(lactic acid)/poly(trimethylene terephthalate) blends for composites with enhanced electrical and thermal conductivities
Popis výsledku v původním jazyce
Interfacial localization of conductive fillers in a cocontinuous immiscible polymer blend is an efficient way of improving the electrical and thermal conductivities of the composite. Conductive path formation at the interface of a cocontinuous structure is expected to provide high conductivity by a smaller amount of the filler, which can be used for applications as conductive materials. In this study, biobased poly(lactic acid) (PLA) was blended with poly(trimethylene terephthalate) (PTT) to make the cocontinuous immiscible polymer blend. Poly(glycidyl methacrylate) (PGMA) was grafted on reduced graphene oxide (rGO) to make a PGMA-grafted rGO (rGO-PGMA). The epoxy group of GMA on rGO-PGMA reacted with the end groups of both PLA and PTT and localized at the interface between PLA and PTT by a two-step blending procedure to form the conductive path between PLA and PTT. From transmission electron microscopy observation, it was found that rGO-PGMA localized between the interface of PLA and PTT. Both electrical and thermal conductivities of the composite were improved, which was confirmed by the electrical volume resistivity and thermal diffusivity measurements, compared with neat polymers and other blends.
Název v anglickém jazyce
Localization of poly(glycidyl methacrylate) grafted on reduced graphene oxide in poly(lactic acid)/poly(trimethylene terephthalate) blends for composites with enhanced electrical and thermal conductivities
Popis výsledku anglicky
Interfacial localization of conductive fillers in a cocontinuous immiscible polymer blend is an efficient way of improving the electrical and thermal conductivities of the composite. Conductive path formation at the interface of a cocontinuous structure is expected to provide high conductivity by a smaller amount of the filler, which can be used for applications as conductive materials. In this study, biobased poly(lactic acid) (PLA) was blended with poly(trimethylene terephthalate) (PTT) to make the cocontinuous immiscible polymer blend. Poly(glycidyl methacrylate) (PGMA) was grafted on reduced graphene oxide (rGO) to make a PGMA-grafted rGO (rGO-PGMA). The epoxy group of GMA on rGO-PGMA reacted with the end groups of both PLA and PTT and localized at the interface between PLA and PTT by a two-step blending procedure to form the conductive path between PLA and PTT. From transmission electron microscopy observation, it was found that rGO-PGMA localized between the interface of PLA and PTT. Both electrical and thermal conductivities of the composite were improved, which was confirmed by the electrical volume resistivity and thermal diffusivity measurements, compared with neat polymers and other blends.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
20505 - Composites (including laminates, reinforced plastics, cermets, combined natural and synthetic fibre fabrics; filled composites)
Návaznosti výsledku
Projekt
—
Návaznosti
V - Vyzkumna aktivita podporovana z jinych verejnych zdroju
Ostatní
Rok uplatnění
2021
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
ACS Applied Nano Materials
ISSN
2574-0970
e-ISSN
—
Svazek periodika
4
Číslo periodika v rámci svazku
8
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
9
Strana od-do
—
Kód UT WoS článku
000692034900096
EID výsledku v databázi Scopus
2-s2.0-85112415810