Assessing PFAS in drinking water: Insights from the Czech Republic’s risk-based monitoring approach

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F75010330%3A_____%2F25%3A00015206" target="_blank" >RIV/75010330:_____/25:00015206 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/60461373:22330/25:43933107

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0045653524028777?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0045653524028777?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.chemosphere.2024.143969" target="_blank" >10.1016/j.chemosphere.2024.143969</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Assessing PFAS in drinking water: Insights from the Czech Republic’s risk-based monitoring approach

Popis výsledku v původním jazyce

This study investigates the presence of perfluoroalkyl substances (PFAS) in the drinking water supplies in the Czech Republic using a risk-based monitoring approach. Tap water samples (n = 27) from sources close to areas potentially contaminated with PFAS were analysed. A total of 28 PFAS were measured using ultra-performance liquid chromatography with tandem mass spectrometry after solid phase extraction. Total PFAS concentrations (?PFAS) varied from undetectable to 90.8 ng/L, with perfluoropentanoic acid (PFPeA), perfluorohexanoic acid (PFHxA), perfluoroheptanoic acid (PFHpA) and perfluorobutane sulfonic acid (PFBS) being the most abundant, detected in over 70% of samples. Risk-based monitoring in drinking water showed that commercial wells had higher PFAS levels compared to tap water, particularly C4–C9 perfluorocarboxylic acids (PFCAs), possibly due to proximity to industrial areas. However, the hypothesis that risk-based monitoring is more effective than random monitoring was not confirmed, possibly because specific sources did not produce the target PFAS or because of the wide range and less obvious sources of potential contamination. The study also assessed exposure risks and compliance with regulatory thresholds. Weekly intake estimates for adults and children indicated that regular consumption of most contaminated water sample would exceed the tolerable weekly intake. Compared to EU regulations, none of the tap water samples exceeded the 'Sum of PFAS' parametric value of 100 ng/L, though one sample approached this limit. In addition, surface water samples from the Jizera River (n = 21) showed a wider range of PFAS, with C7–C10 PFCAs, PFBS, and perfluorooctane sulfonic acid (PFOS) in every sample, with higher PFOS concentrations at a median of 2.56 ng/L. ?PFAS concentrations increased downstream, rising from 1.08 ng/L near the spring to 26 ng/L downstream. This comprehensive analysis highlights the need for detailed/areal monitoring to also address hidden or non-obvious sources of PFAS contamination.

Název v anglickém jazyce

Assessing PFAS in drinking water: Insights from the Czech Republic’s risk-based monitoring approach

Popis výsledku anglicky

This study investigates the presence of perfluoroalkyl substances (PFAS) in the drinking water supplies in the Czech Republic using a risk-based monitoring approach. Tap water samples (n = 27) from sources close to areas potentially contaminated with PFAS were analysed. A total of 28 PFAS were measured using ultra-performance liquid chromatography with tandem mass spectrometry after solid phase extraction. Total PFAS concentrations (?PFAS) varied from undetectable to 90.8 ng/L, with perfluoropentanoic acid (PFPeA), perfluorohexanoic acid (PFHxA), perfluoroheptanoic acid (PFHpA) and perfluorobutane sulfonic acid (PFBS) being the most abundant, detected in over 70% of samples. Risk-based monitoring in drinking water showed that commercial wells had higher PFAS levels compared to tap water, particularly C4–C9 perfluorocarboxylic acids (PFCAs), possibly due to proximity to industrial areas. However, the hypothesis that risk-based monitoring is more effective than random monitoring was not confirmed, possibly because specific sources did not produce the target PFAS or because of the wide range and less obvious sources of potential contamination. The study also assessed exposure risks and compliance with regulatory thresholds. Weekly intake estimates for adults and children indicated that regular consumption of most contaminated water sample would exceed the tolerable weekly intake. Compared to EU regulations, none of the tap water samples exceeded the 'Sum of PFAS' parametric value of 100 ng/L, though one sample approached this limit. In addition, surface water samples from the Jizera River (n = 21) showed a wider range of PFAS, with C7–C10 PFCAs, PFBS, and perfluorooctane sulfonic acid (PFOS) in every sample, with higher PFOS concentrations at a median of 2.56 ng/L. ?PFAS concentrations increased downstream, rising from 1.08 ng/L near the spring to 26 ng/L downstream. This comprehensive analysis highlights the need for detailed/areal monitoring to also address hidden or non-obvious sources of PFAS contamination.

Druh

J_SC - Článek v periodiku v databázi SCOPUS

CEP obor

—

OECD FORD obor

30304 - Public and environmental health

Projekt

<a href="/cs/project/LM2018100" target="_blank" >LM2018100: Infrastruktura pro propagaci metrologie v potravinářství a výživě v České republice</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2025

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Chemosphere

ISSN

0045-6535

e-ISSN

1879-1298

Svazek periodika

370

Číslo periodika v rámci svazku

February

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

9

Strana od-do

143969

Kód UT WoS článku

—

EID výsledku v databázi Scopus

2-s2.0-85213080715