Spatiotemporal Control of the Formation of Luminescent Lanthanide Complexes in Liposome-Based Nanoreactors

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14160%2F25%3A00142122" target="_blank" >RIV/00216224:14160/25:00142122 - isvavai.cz</a>
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/10.1002/anie.202510471" target="_blank" >https://onlinelibrary.wiley.com/doi/10.1002/anie.202510471</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.202510471" target="_blank" >10.1002/anie.202510471</a>

Result language
angličtina
Original language name
Spatiotemporal Control of the Formation of Luminescent Lanthanide Complexes in Liposome-Based Nanoreactors
Original language description
The controlled mass transfer across compartmentalised environments in synthetic nanoreactors is essential for enhancing precise spatiotemporal manipulation of chemical transformations within confined spaces. In this study, we present a strategy that integrates a synthetic anion transporter in liposome-based nanoreactors, allowing for spatiotemporal control over the formation of metal-organic complexes in liposomes. This approach enables us to effectively modulate the assembly of luminescent lanthanide-benzenedicarboxylate nanostructures. Fluorescence studies demonstrate that the reaction rate can be customised by varying the anion transporter concentration, which dictates the rate of entry of the carboxylate ligand. Changes in the morphology of the liposome nanoreactors due to the assisted transmembrane transport of benzenedicarboxylate were investigated using cryo-TEM and time-resolved SAXS measurements, which revealed a structural transformation of the lipid bilayer during the complex formation. Our findings provide a novel platform for exploring coordination chemistry in nanoscale confinements, opening avenues for the design of biohybrid materials.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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