Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898096" target="_blank" >RIV/00216275:25310/14:39898096 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jorganchem.2014.09.028" target="_blank" >http://dx.doi.org/10.1016/j.jorganchem.2014.09.028</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2014.09.028" target="_blank" >10.1016/j.jorganchem.2014.09.028</a>

Result language
angličtina
Original language name
Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands
Original language description
The reactivity of cyclopentadienyl and indenyl molybdenum(II) complexes [(h5-Cp')Mo(CO)2(NCMe)2] [BF4] (Cp' = Cp, Ind, 1,3-Ph2C9H5) with a series of planar N,N,N-chelating ligands was scrutinized. In particular cases a spontaneous release of carbon monoxide to give [(h5-Cp')Mo(CO)(k3-N,N,NL)][BF4] depending on several factors including the basicity of the tridentate ligand as well as the nature of the starting molybdenum(II) compound. This behaviour strongly contrasts with tripodal ligands those do notaffect cis-Mo(CO)2 moiety even upon tridentate coordination. All structure types, discussed in this work, were elucidated by the spectroscopic measurements as well as by the X-ray crystallography.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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