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Structure and properties of Hf-O-N films prepared by high-rate reactive HiPIMS with smoothly controlled composition

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F49777513%3A23520%2F17%3A43931447" target="_blank" >RIV/49777513:23520/17:43931447 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11320/17:10371320

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.ceramint.2017.01.102" target="_blank" >http://dx.doi.org/10.1016/j.ceramint.2017.01.102</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.ceramint.2017.01.102" target="_blank" >10.1016/j.ceramint.2017.01.102</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Structure and properties of Hf-O-N films prepared by high-rate reactive HiPIMS with smoothly controlled composition

  • Original language description

    Hafnium oxynitride ceramics were prepared in the form of thin films by high-power impulse magnetron sputtering of Hf in various Ar+O2+N2 gas mixtures. Smooth composition control was achieved by maximizing the degree of dissociation in plasma, suppressing the importance of the difference between reactivities of undissociated O2 and N2. The application potential of the films was further enhanced by extremely high deposition rates (e.g. 230 nm/min for stoichiometric HfO2; achieved by feedback pulsed reactive gas flow control), low deposition temperatures (&lt; 140 °C) and not using any substrate bias. We focus on the relationships between elemental composition, phase structure, and optical, electrical, mechanical and hydrophobic properties of the materials. We quantify the evolution of smoothly controlled film properties along the transition from an oxide to a nitride, such as increasing extinction coefficient, decreasing electrical resistivity, increasing hardness or increasing water droplet contact angle.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20506 - Coating and films

Result continuities

  • Project

    <a href="/en/project/GA14-03875S" target="_blank" >GA14-03875S: Nanostructured multifunctional coatings prepared using highly ionized pulsed plasmas</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2017

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    CERAMICS INTERNATIONAL

  • ISSN

    0272-8842

  • e-ISSN

  • Volume of the periodical

    43

  • Issue of the periodical within the volume

    7

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    7

  • Pages from-to

    5661-5667

  • UT code for WoS article

    000397075900041

  • EID of the result in the Scopus database

    2-s2.0-85010555673