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Ion and atom fluxes during HiPIMS deposition of NbC from a compound target

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F49777513%3A23520%2F23%3A43969229" target="_blank" >RIV/49777513:23520/23:43969229 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Ion and atom fluxes during HiPIMS deposition of NbC from a compound target

  • Original language description

    Sputtered element ratio (Nb/C) in films deposited from a compound NbC target by non-reactive high power impulse magnetron sputtering (HiPIMS) operated at different frequencies and duty cycles have been investigated. Time-averaged mass spectrometry shows that the fluxes of sputtered target ions increase with increasing pulse power density (and decreasing pulse length) due to increasing the electron density and, hence, electron-impact ionization probability. Since Nb atoms have lower ionization energy and larger ionization cross-section than C atoms, the Nb ions dominate the flux of ions onto the film at all conditions. Neutrals were monitored by optical emission spectroscopy (OES) and showed a decrease by increasing pulse power density. In the case of 500 Hz, the Nb/C ratio varied from 0.6 to 0.95 by adjusting the length of HiPIMS pulses between 200 μs and 30 μs, achieving nearly stoichiometric composition for the lowest pulse length.

  • Czech name

  • Czech description

Classification

  • Type

    O - Miscellaneous

  • CEP classification

  • OECD FORD branch

    20506 - Coating and films

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů