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Helium-Assisted Glancing Angle Deposition of Thin Films of TiCuOx and WOx for Conductometric Hydrogen Sensing

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F49777513%3A23520%2F24%3A43972649" target="_blank" >RIV/49777513:23520/24:43972649 - isvavai.cz</a>

  • Alternative codes found

    RIV/49777513:23520/24:43972654 RIV/49777513:23520/24:43973139

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Helium-Assisted Glancing Angle Deposition of Thin Films of TiCuOx and WOx for Conductometric Hydrogen Sensing

  • Original language description

    In the quest for efficient hydrogen detection, the limitations of current sensors – such as low sensitivity and selectivity – pose significant challenges. Advancements in hydrogen sensing materials and techniques are essential to improve safety and efficiency. This study pioneers a novel helium-assisted sputter deposition technique for TiCuOx and WOx films, targeting enhancement of active surface area and therefore improvement of sensing performance. We also describe how a helium-rich working atmosphere induces changes in the structure of the thin films. TiCuOx films were deposited using conventional DC magnetron sputtering, employing a circular titanium target with adjacent copper strip in various working gas mixtures of argon, helium, and oxygen, with fixed value of total pressure of approximately 520 mPa. The glancing angle deposition (GLAD) technique was initially employed to induce a columnar nanostructure, increasing the films&apos; surface roughness and porosity and thereby enhancing hydrogen interaction. Accompanying GLAD, helium was introduced as a replacement for part of argon to modify the TiCuOx films&apos; surface characteristics further.

  • Czech name

  • Czech description

Classification

  • Type

    O - Miscellaneous

  • CEP classification

  • OECD FORD branch

    20506 - Coating and films

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2024

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů