Structural and magnetic characterizations of the first manganese(III) Schiff base complexes involving hexathiocyanidoplatinate(IV) bridges

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F13%3A33145827" target="_blank" >RIV/61989592:15310/13:33145827 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/c3ce40524a" target="_blank" >http://dx.doi.org/10.1039/c3ce40524a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c3ce40524a" target="_blank" >10.1039/c3ce40524a</a>

Result language
angličtina
Original language name
Structural and magnetic characterizations of the first manganese(III) Schiff base complexes involving hexathiocyanidoplatinate(IV) bridges
Original language description
The reactions of [MnIII(L4a)Cl] or [MnIII(L4b)Cl] with [Pt(SCN)6]22 resulted in the formation of a 1D polymeric complex [{Mn(L4a)}2{m-Pt(SCN)6}]n (1) and a trinuclear compound [{Mn(L4b)(H2O)}2{m-Pt(SCN)6}] (2), where L4a and L4b are tetradentate dianionic Schiff base ligands, H2L4a = N,N9-ethylenebis(salicylimine) and H2L4b = N,N9-3-methylbenzenebis(3-ethoxysalicylimine). In compound 1, the adjacent [Mn(L4a)]+ subunits are bound together through the phenolic oxygen atoms, thus forming [{Mn(L4a)}2]2+ dimers with the shortest Mn...Mn distance of 3.2101(5) ?, while in compound 2, the intermolecular bifurcated O-H...O hydrogen bonds between the neighbouring molecules form [{Mn(L4b)(H2O)}2]2+ dimers, resulting in a supramolecular 1D chain structure. The Mn...Mn distance within the supramolecular dimer is 4.7007(9) ?, while the shortest Mn...Mn distance between the dimers is 9.2347(10) ?. The magnetic analyses comprising the zero-field splitting resulted in a ferromagnetic exchange interacti
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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