Use of silver carbonate in the Wittig reaction

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F13%3A33147711" target="_blank" >RIV/61989592:15310/13:33147711 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/jo401972a" target="_blank" >http://dx.doi.org/10.1021/jo401972a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/jo401972a" target="_blank" >10.1021/jo401972a</a>

Result language
angličtina
Original language name
Use of silver carbonate in the Wittig reaction
Original language description
An efficient synthesis of olefins by the coupling of stabilized, semistabilized, and nonstabilized phosphorus ylides with various carbonyl compounds in the presence of silver carbonate is reported. Wittig olefination of aromatic, heteroaromatic, and aliphatic aldehydes (yields }63%) and a ketone (yield 42%) are demonstrated. These reactions proceed overnight at room temperature, under weakly basic conditions, and as such extend the applicability of the Wittig reaction to base-sensitive reactants.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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