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Thermodynamic stability and energetics of DNA duplexes containing major intrastrand cross-links of second-generation antitumor dinuclear Pt-II complexes

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081707%3A_____%2F12%3A00389601" target="_blank" >RIV/68081707:_____/12:00389601 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s00775-011-0841-4" target="_blank" >http://dx.doi.org/10.1007/s00775-011-0841-4</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s00775-011-0841-4" target="_blank" >10.1007/s00775-011-0841-4</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Thermodynamic stability and energetics of DNA duplexes containing major intrastrand cross-links of second-generation antitumor dinuclear Pt-II complexes

  • Original language description

    The effects of major DNA intrastrand cross-links of antitumor dinuclear Pt-II complexes [{trans-PtCl(NH3)(2)}(2)-mu-{trans-(H2N(CH2)(6)NH2(CH2)(2)NH2(CH2)(6) NH2)}](4+) (1) and [{PtCl(DACH)}(2)-mu-{H2N(CH2)(6)NH2 (CH2)(2)NH2(CH2)(6)NH2)}](4+) (2) (DACH is 1,2-diaminocyclohexane) on DNA stability were studied with emphasis on thermodynamic origins of that stability. Oligodeoxyribonucleotide duplexes containing the single 1,2, 1,3, or 1,5 intrastrand cross-links at guanine residues in the central TGGT, TGTGT, or TGTTTGT sequences, respectively, were prepared and analyzed by differential scanning calorimetry. The unfolding of the platinated duplexes was accompanied by unfavorable free energy terms.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BO - Biophysics

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Biological Inorganic Chemistry

  • ISSN

    0949-8257

  • e-ISSN

  • Volume of the periodical

    17

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    10

  • Pages from-to

    187-196

  • UT code for WoS article

    000301185800003

  • EID of the result in the Scopus database