The Coordination Behaviour of Ferrocene-based Pyridylphosphine Ligands towards Ag(I) and Au(I)

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F11%3A10101068" target="_blank" >RIV/00216208:11310/11:10101068 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1002/zaac.201100209" target="_blank" >http://dx.doi.org/10.1002/zaac.201100209</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/zaac.201100209" target="_blank" >10.1002/zaac.201100209</a>

Jazyk výsledku

angličtina

Název v původním jazyce

The Coordination Behaviour of Ferrocene-based Pyridylphosphine Ligands towards Ag(I) and Au(I)

Popis výsledku v původním jazyce

The reaction of the P,N-ligands [Fe(C5H4PPh2)(C5H4-2-py)] (1) (2-py = pyrid-2-yl), [Fe(C5H4PPh2)(C5H4CH2-2-py)] (2) and [Fe(C5H4PPh2)(C5H4-3-py)] (3) (3-py = pyrid-3-yl) with Ag[BF(4)] in a 1:1 stoichiometric ratio afforded complexes of the type [Ag(L)][BF(4)] (L = 1-3), which were structurally characterised by X-ray diffraction. Two structure types were observed in the solid state, viz. coordination polymer (L = 1, 2) and cyclic dimer (L = 2, 3). The reaction of 1-3 with one equivalent of [AuCl(tht)] (tht = tetrahydrothiophene) afforded complexes of the type [AuCl(L-kappa P)] (L = 1-3), whose crystal structures were determined by X-ray diffraction. Their reactions with one equivalent of Ag[BF4] gave products of the general composition [Au(L)][BF4]; ofthese the cyclic dimer {[Au(mu-1)][BF4]}2 was structurally characterised by X-ray diffraction. The P,N,P-ligand C5H3N-2,6-(fcPPh2)2 (4, fc = 1,1'-ferrocenediyl) was also synthesised and studied.

Název v anglickém jazyce

The Coordination Behaviour of Ferrocene-based Pyridylphosphine Ligands towards Ag(I) and Au(I)

Popis výsledku anglicky

The reaction of the P,N-ligands [Fe(C5H4PPh2)(C5H4-2-py)] (1) (2-py = pyrid-2-yl), [Fe(C5H4PPh2)(C5H4CH2-2-py)] (2) and [Fe(C5H4PPh2)(C5H4-3-py)] (3) (3-py = pyrid-3-yl) with Ag[BF(4)] in a 1:1 stoichiometric ratio afforded complexes of the type [Ag(L)][BF(4)] (L = 1-3), which were structurally characterised by X-ray diffraction. Two structure types were observed in the solid state, viz. coordination polymer (L = 1, 2) and cyclic dimer (L = 2, 3). The reaction of 1-3 with one equivalent of [AuCl(tht)] (tht = tetrahydrothiophene) afforded complexes of the type [AuCl(L-kappa P)] (L = 1-3), whose crystal structures were determined by X-ray diffraction. Their reactions with one equivalent of Ag[BF4] gave products of the general composition [Au(L)][BF4]; ofthese the cyclic dimer {[Au(mu-1)][BF4]}2 was structurally characterised by X-ray diffraction. The P,N,P-ligand C5H3N-2,6-(fcPPh2)2 (4, fc = 1,1'-ferrocenediyl) was also synthesised and studied.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2011

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Zeitschrift für Anorganische und Allgemeine Chemie

ISSN

0044-2313

e-ISSN

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Svazek periodika

637

Číslo periodika v rámci svazku

12

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

10

Strana od-do

1824-1833

Kód UT WoS článku

000296856300027

EID výsledku v databázi Scopus

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