Heterodinuclear Arene Ruthenium Complexes Containing a Glycine-Derived Phosphinoferrocene Carboxamide: Synthesis, Molecular Structure, Electrochemistry, and Catalytic Oxidation Activity in Aqueous Media

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10126168" target="_blank" >RIV/00216208:11310/12:10126168 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1021/om3002087" target="_blank" >http://dx.doi.org/10.1021/om3002087</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/om3002087" target="_blank" >10.1021/om3002087</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Heterodinuclear Arene Ruthenium Complexes Containing a Glycine-Derived Phosphinoferrocene Carboxamide: Synthesis, Molecular Structure, Electrochemistry, and Catalytic Oxidation Activity in Aqueous Media

Popis výsledku v původním jazyce

Three series of heterodinuclear ruthenium iron complexes have been synthesized from (eta(6)-arene)ruthenium dichloride dimers and phosphinoferrocene ligands containing glycine-based carboxamido substituents. The neutral complexes [(eta(6)-arene)RuCl2(Ph2PfcCONHCH2CO2Me-kappa P)] (4, arene = benzene (a), p-cymene (b), hexamethylbenzene (c); fc = ferrocene-1,1'-diyl) were obtained by the bridge cleavage reaction of [(eta(6)-arene)RuCl2](2) with Ph2PfcCONHCH2CO2Me (1) in chloroform solution. The complex [(eta(6)-p-cymene)RuCl2(Ph2PfcCONHCH2CONH2-kappa P)] (6b) was synthesized in the same way from Ph2PfcCONHCH2CONH2 (3); the preparation of [(eta(6)-p-cymene)RuCl2(Ph2PfcCONHCH2CO2H-kappa P)] (5b), featuring the ferrocene ligand in the free acid form (2), failed due to side reactions and isolation problems. The salts [(eta(6)-arene)RuCl(MeCN)(1-kappa P)][PF6] (7a-c) and [(eta(6)-arene)Ru(MeCN)2(1-kappa P)][PF6]2 (8a-c) were prepared from 1 and the acetonitrile precursors [(eta(6)-arene)RuCl(

Název v anglickém jazyce

Heterodinuclear Arene Ruthenium Complexes Containing a Glycine-Derived Phosphinoferrocene Carboxamide: Synthesis, Molecular Structure, Electrochemistry, and Catalytic Oxidation Activity in Aqueous Media

Popis výsledku anglicky

Three series of heterodinuclear ruthenium iron complexes have been synthesized from (eta(6)-arene)ruthenium dichloride dimers and phosphinoferrocene ligands containing glycine-based carboxamido substituents. The neutral complexes [(eta(6)-arene)RuCl2(Ph2PfcCONHCH2CO2Me-kappa P)] (4, arene = benzene (a), p-cymene (b), hexamethylbenzene (c); fc = ferrocene-1,1'-diyl) were obtained by the bridge cleavage reaction of [(eta(6)-arene)RuCl2](2) with Ph2PfcCONHCH2CO2Me (1) in chloroform solution. The complex [(eta(6)-p-cymene)RuCl2(Ph2PfcCONHCH2CONH2-kappa P)] (6b) was synthesized in the same way from Ph2PfcCONHCH2CONH2 (3); the preparation of [(eta(6)-p-cymene)RuCl2(Ph2PfcCONHCH2CO2H-kappa P)] (5b), featuring the ferrocene ligand in the free acid form (2), failed due to side reactions and isolation problems. The salts [(eta(6)-arene)RuCl(MeCN)(1-kappa P)][PF6] (7a-c) and [(eta(6)-arene)Ru(MeCN)2(1-kappa P)][PF6]2 (8a-c) were prepared from 1 and the acetonitrile precursors [(eta(6)-arene)RuCl(

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

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Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2012

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Organometallics

ISSN

0276-7333

e-ISSN

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Svazek periodika

31

Číslo periodika v rámci svazku

10

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

10

Strana od-do

3985-3994

Kód UT WoS článku

000304385600022

EID výsledku v databázi Scopus

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