Mossbauerite as Iron-Only Layered Oxyhydroxide Catalyst for WO3 Photoanodes
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F19%3A10403402" target="_blank" >RIV/00216208:11310/19:10403402 - isvavai.cz</a>
Výsledek na webu
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=OuxdCEc6c4" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=OuxdCEc6c4</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.inorgchem.9b00327" target="_blank" >10.1021/acs.inorgchem.9b00327</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Mossbauerite as Iron-Only Layered Oxyhydroxide Catalyst for WO3 Photoanodes
Popis výsledku v původním jazyce
Mossbauerite, a trivalent iron-only layered oxyhydroxide, has been recently identified as an electrocatalyst for water oxidation. We investigated the material as potential cocatalyst for photoelectrochemical water oxidation on semiconductor photoanodes. The band edge positions of mossbauerite were determined for the first time with a combination of Mott-Schottky analysis and UV-vis diffuse reflectance spectroscopy. The positive value of the Mott-Schottky slope and the flatband potential of 0.34 V vs reversible hydrogen electrode (RHE) identifies the material as an n-type semiconductor, but bare mossbauerite does not produce noticeable photocurrent during water oxidation. Type-II heterojunction formation by facile drop-casting with WO3 thin films yielded photoanodes with amended charge carrier separation and photocurrents up to 1.22 mA cm(-2) at 1.23 V vs RHE. Mossbauerite is capable of increasing the charge carrier separation at lower potential and improving the photocurrent during photoelectrochemical water oxidation. The rise in photocurrent of the mossbauerite-functionalized WO3 photoanode thus originates from improved charge carrier separation and augmented hole collection efficiency. Our results highlight the potential of mossbauerite as a second-phase catalyst for semiconductor electrodes.
Název v anglickém jazyce
Mossbauerite as Iron-Only Layered Oxyhydroxide Catalyst for WO3 Photoanodes
Popis výsledku anglicky
Mossbauerite, a trivalent iron-only layered oxyhydroxide, has been recently identified as an electrocatalyst for water oxidation. We investigated the material as potential cocatalyst for photoelectrochemical water oxidation on semiconductor photoanodes. The band edge positions of mossbauerite were determined for the first time with a combination of Mott-Schottky analysis and UV-vis diffuse reflectance spectroscopy. The positive value of the Mott-Schottky slope and the flatband potential of 0.34 V vs reversible hydrogen electrode (RHE) identifies the material as an n-type semiconductor, but bare mossbauerite does not produce noticeable photocurrent during water oxidation. Type-II heterojunction formation by facile drop-casting with WO3 thin films yielded photoanodes with amended charge carrier separation and photocurrents up to 1.22 mA cm(-2) at 1.23 V vs RHE. Mossbauerite is capable of increasing the charge carrier separation at lower potential and improving the photocurrent during photoelectrochemical water oxidation. The rise in photocurrent of the mossbauerite-functionalized WO3 photoanode thus originates from improved charge carrier separation and augmented hole collection efficiency. Our results highlight the potential of mossbauerite as a second-phase catalyst for semiconductor electrodes.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10402 - Inorganic and nuclear chemistry
Návaznosti výsledku
Projekt
—
Návaznosti
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2019
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Inorganic Chemistry
ISSN
0020-1669
e-ISSN
—
Svazek periodika
58
Číslo periodika v rámci svazku
15
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
8
Strana od-do
9655-9662
Kód UT WoS článku
000480371400020
EID výsledku v databázi Scopus
2-s2.0-85070852740