Some novel porous materials for selective catalytic oxidations

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F20%3A10419851" target="_blank" >RIV/00216208:11310/20:10419851 - isvavai.cz</a>

Výsledek na webu

<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=SVksQrsyjx" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=SVksQrsyjx</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.mattod.2019.06.008" target="_blank" >10.1016/j.mattod.2019.06.008</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Some novel porous materials for selective catalytic oxidations

Popis výsledku v původním jazyce

Porous materials are outstanding catalysts in various reactions using confinement and shape selectivity effects. Unsurprisingly, extensive research has been conducted on zeolites, pillared clays, metal oxides, metal organic frameworks, and mesoporous materials. In particular, selective oxidation of hydrocarbons stands out an important class of reactions, but the ability to avoid over-oxidation remains a challenge. Thus, the present review highlights the latest findings on octahedral and tetrahedral catalytic materials in oxidation reactions, primarily focusing on types of reactive oxygen species and approaches to their investigation, on the incorporation of different heteroatoms (Ti, Sn) into silica matrices for catalytic purposes and corresponding types of reactions and on surface engineering and design of &quot;single-site catalysts&quot;. In addition, composite catalysts for one-pot selective oxidation reactions are reviewed, providing examples from photochemistry including &quot;single-site photocatalysis&quot;, electrocatalysis, and integration of metal complexes with functional solid materials. Ultimately, the end goal of this review is to discuss current state-of-the-art approaches that are being used in the area of selective catalytic oxidations with some novel porous materials. This includes methods that are being used to study mechanistic details as well as new catalysts and new substrates for such oxidations.

Název v anglickém jazyce

Some novel porous materials for selective catalytic oxidations

Popis výsledku anglicky

Porous materials are outstanding catalysts in various reactions using confinement and shape selectivity effects. Unsurprisingly, extensive research has been conducted on zeolites, pillared clays, metal oxides, metal organic frameworks, and mesoporous materials. In particular, selective oxidation of hydrocarbons stands out an important class of reactions, but the ability to avoid over-oxidation remains a challenge. Thus, the present review highlights the latest findings on octahedral and tetrahedral catalytic materials in oxidation reactions, primarily focusing on types of reactive oxygen species and approaches to their investigation, on the incorporation of different heteroatoms (Ti, Sn) into silica matrices for catalytic purposes and corresponding types of reactions and on surface engineering and design of &quot;single-site catalysts&quot;. In addition, composite catalysts for one-pot selective oxidation reactions are reviewed, providing examples from photochemistry including &quot;single-site photocatalysis&quot;, electrocatalysis, and integration of metal complexes with functional solid materials. Ultimately, the end goal of this review is to discuss current state-of-the-art approaches that are being used in the area of selective catalytic oxidations with some novel porous materials. This includes methods that are being used to study mechanistic details as well as new catalysts and new substrates for such oxidations.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

<a href="/cs/project/GX19-27551X" target="_blank" >GX19-27551X: ADORable katalyzátory</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Materials Today

ISSN

1369-7021

e-ISSN

—

Svazek periodika

32

Číslo periodika v rámci svazku

Jan-Feb

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

16

Strana od-do

244-259

Kód UT WoS článku

000514670500035

EID výsledku v databázi Scopus

2-s2.0-85071384495