Adsorptive stripping voltammetric determination of carbofuran in food using novel type of modified carbon-based electrode with grafted layers of nickel

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F24%3A10487993" target="_blank" >RIV/00216208:11310/24:10487993 - isvavai.cz</a>

Výsledek na webu

<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=HGCmZe9XJ2" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=HGCmZe9XJ2</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.talanta.2023.125116" target="_blank" >10.1016/j.talanta.2023.125116</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Adsorptive stripping voltammetric determination of carbofuran in food using novel type of modified carbon-based electrode with grafted layers of nickel

Popis výsledku v původním jazyce

A voltammetric determination of carbofuran (CBF) was developed using a novel type of carbon-containing electrode (CCE) modified with carbon ink (CI) and a chromatographic sorbent (CS) based of chromaton (Ch), polyethylene glycol and nickel acetylacetonate with grafted layers of nickel (NiCS, stands for Ni modified CS) further denoted as CI/NiCS/CCE. The surface morphology of this modified electrode was investigated by scanning electron microscopy (SEM) and by electrochemical impedance spectroscopy (EIS). CBF which is not electrochemically oxidizable was first hydrolyzed in alkaline medium to give anodically active phenolic analogue CBFP. The electrochemical reactions of CBFP at CI/NiCS/CCE were studied in phosphate buffer (PB) by cyclic voltammetry (CV) and linear sweep adsorptive stripping voltammetry (LSAdSV) using linear scan voltammetry in the first derivative mode (LSVFD). Linear concentration dependences in the concentration ranges from 0.1 to 10 μM and from 10 to 100 μM were obtained by the LSAdSV with limit of detection (LOD) and limit of quantification (LOQ) 0.06 and 0.19 μM, respectively. The novel modified CI/NiCS/CCE showed good stability and selectivity and was successfully used to determine CBF in real samples of vegetables and fruits with LOD 0.01 mg kg(-1).

Název v anglickém jazyce

Adsorptive stripping voltammetric determination of carbofuran in food using novel type of modified carbon-based electrode with grafted layers of nickel

Popis výsledku anglicky

A voltammetric determination of carbofuran (CBF) was developed using a novel type of carbon-containing electrode (CCE) modified with carbon ink (CI) and a chromatographic sorbent (CS) based of chromaton (Ch), polyethylene glycol and nickel acetylacetonate with grafted layers of nickel (NiCS, stands for Ni modified CS) further denoted as CI/NiCS/CCE. The surface morphology of this modified electrode was investigated by scanning electron microscopy (SEM) and by electrochemical impedance spectroscopy (EIS). CBF which is not electrochemically oxidizable was first hydrolyzed in alkaline medium to give anodically active phenolic analogue CBFP. The electrochemical reactions of CBFP at CI/NiCS/CCE were studied in phosphate buffer (PB) by cyclic voltammetry (CV) and linear sweep adsorptive stripping voltammetry (LSAdSV) using linear scan voltammetry in the first derivative mode (LSVFD). Linear concentration dependences in the concentration ranges from 0.1 to 10 μM and from 10 to 100 μM were obtained by the LSAdSV with limit of detection (LOD) and limit of quantification (LOQ) 0.06 and 0.19 μM, respectively. The novel modified CI/NiCS/CCE showed good stability and selectivity and was successfully used to determine CBF in real samples of vegetables and fruits with LOD 0.01 mg kg(-1).

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10406 - Analytical chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Talanta

ISSN

0039-9140

e-ISSN

1873-3573

Svazek periodika

267

Číslo periodika v rámci svazku

January

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

8

Strana od-do

125116

Kód UT WoS článku

001236163600001

EID výsledku v databázi Scopus

2-s2.0-85171157758