Inorganic-Organic Hybrid Materials: Layered Zinc Hydroxide Salts with Intercalated Porphyrin Sensitizers

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F10%3A10082010" target="_blank" >RIV/00216208:11320/10:10082010 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61388980:_____/10:00349658 RIV/61388955:_____/10:00349658

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Inorganic-Organic Hybrid Materials: Layered Zinc Hydroxide Salts with Intercalated Porphyrin Sensitizers

Popis výsledku v původním jazyce

Layered materials provide a two-dimensional interlayer space suitable for accommodating molecules with a designed functionality. In this study, inorganic-organic hybrids were prepared by intercalation of anionic porphyrin sensitizers into the host structure of layered zinc hydroxide salts. The inorganic host offers stabilization and protection, whereas the guest species provide the photofunction. The properties and arrangement of porphyrin molecules in the interlayer space were studied by a combinationof experimental techniques and molecular simulations. Intercalation of porphyrins led to a gallery height that is comparable with the size of porphyrin molecules. Molecular simulations showed that the interlayer space is filled with disordered porphyrinunits.The porphyrin sulfonate groups interact with the brucite-like layers via dominant electrostatic interactions similarly to layered double hydroxides.

Název v anglickém jazyce

Inorganic-Organic Hybrid Materials: Layered Zinc Hydroxide Salts with Intercalated Porphyrin Sensitizers

Popis výsledku anglicky

Layered materials provide a two-dimensional interlayer space suitable for accommodating molecules with a designed functionality. In this study, inorganic-organic hybrids were prepared by intercalation of anionic porphyrin sensitizers into the host structure of layered zinc hydroxide salts. The inorganic host offers stabilization and protection, whereas the guest species provide the photofunction. The properties and arrangement of porphyrin molecules in the interlayer space were studied by a combinationof experimental techniques and molecular simulations. Intercalation of porphyrins led to a gallery height that is comparable with the size of porphyrin molecules. Molecular simulations showed that the interlayer space is filled with disordered porphyrinunits.The porphyrin sulfonate groups interact with the brucite-like layers via dominant electrostatic interactions similarly to layered double hydroxides.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GAP207%2F10%2F1447" target="_blank" >GAP207/10/1447: Fotoaktivní hybridní materiály</a><br>

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2010

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Physical Chemistry C

ISSN

1932-7447

e-ISSN

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Svazek periodika

114

Číslo periodika v rámci svazku

39

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

8

Strana od-do

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Kód UT WoS článku

000282209800034

EID výsledku v databázi Scopus

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