Intercalates of Strontium Phenylphosphonate with Alcohols - Structure Analysis by Experimental and Molecular Modeling Methods

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F15%3A10314737" target="_blank" >RIV/00216208:11320/15:10314737 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61389013:_____/15:00443463 RIV/00216275:25310/15:39899472

Výsledek na webu

<a href="http://dx.doi.org/10.1002/ejic.201403069" target="_blank" >http://dx.doi.org/10.1002/ejic.201403069</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/ejic.201403069" target="_blank" >10.1002/ejic.201403069</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Intercalates of Strontium Phenylphosphonate with Alcohols - Structure Analysis by Experimental and Molecular Modeling Methods

Popis výsledku v původním jazyce

Alcohol intercalated strontium phenylphosphonates were prepared by the addition of alcohols to an aqueous solution of strontium phenylphosphonate (SrPhP). These intercalates are unstable and de-intercalate spontaneously at ambient conditions. For the complete elucidation of their structure, a combination of a single-crystal X-ray diffraction and molecular modeling was used. The structure of the host layers in methanol (SrPhP center dot MeOH) and ethanol (SrPhP center dot EtOH) intercalates is composed of strontium atoms, which are eight-coordinate by oxygen atoms of the phosphonato groups and of water molecules. The structures of SrPhP center dot MeOH and SrPhP center dot EtOH differ in the orientation of the phenyl rings. The alcohol molecules residein the cavities formed by the phenyl rings and are coordinated to the Sr atoms of the host layer through their oxygen atoms. On the basis of the structure of SrPhP center dot EtOH, the structures of propanol and butanol intercalates and o

Název v anglickém jazyce

Intercalates of Strontium Phenylphosphonate with Alcohols - Structure Analysis by Experimental and Molecular Modeling Methods

Popis výsledku anglicky

Alcohol intercalated strontium phenylphosphonates were prepared by the addition of alcohols to an aqueous solution of strontium phenylphosphonate (SrPhP). These intercalates are unstable and de-intercalate spontaneously at ambient conditions. For the complete elucidation of their structure, a combination of a single-crystal X-ray diffraction and molecular modeling was used. The structure of the host layers in methanol (SrPhP center dot MeOH) and ethanol (SrPhP center dot EtOH) intercalates is composed of strontium atoms, which are eight-coordinate by oxygen atoms of the phosphonato groups and of water molecules. The structures of SrPhP center dot MeOH and SrPhP center dot EtOH differ in the orientation of the phenyl rings. The alcohol molecules residein the cavities formed by the phenyl rings and are coordinated to the Sr atoms of the host layer through their oxygen atoms. On the basis of the structure of SrPhP center dot EtOH, the structures of propanol and butanol intercalates and o

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CI - Průmyslová chemie a chemické inženýrství

OECD FORD obor

—

Projekt

<a href="/cs/project/GA14-13368S" target="_blank" >GA14-13368S: 2D struktury na bázi fosfonátů kovů: vztahy mezi uspořádáním a vlastnostmi studované pomocí experimentálních a výpočetních metod</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

European Journal of Inorganic Chemistry

ISSN

1434-1948

e-ISSN

—

Svazek periodika

2015

Číslo periodika v rámci svazku

9

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

10

Strana od-do

1552-1561

Kód UT WoS článku

000351435100009

EID výsledku v databázi Scopus

2-s2.0-84923013546