Intercalation of 1,n-diols into strontium phenylphosphonate: How the shape of the host layers influences arrangement of the guest molecules

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F15%3A10314738" target="_blank" >RIV/00216208:11320/15:10314738 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61389013:_____/15:00448267 RIV/00216275:25310/15:39899473

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.jcis.2015.08.043" target="_blank" >http://dx.doi.org/10.1016/j.jcis.2015.08.043</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jcis.2015.08.043" target="_blank" >10.1016/j.jcis.2015.08.043</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Intercalation of 1,n-diols into strontium phenylphosphonate: How the shape of the host layers influences arrangement of the guest molecules

Popis výsledku v původním jazyce

Strontium phenylphosphonate intercalates with 1,n diols (n = 2-4, 6-8) having general formula SrC6H5PO3 center dot x(HO(CH2)(n)OH)center dot yH(2)O were prepared by precipitation from strontium phenylphosphonate solution and the corresponding diols. Prepared compounds exhibit a very good stability at ambient conditions. The intercalates were characterized by X-ray diffraction, thermogravimetry and elemental analysis. Thanks to the existence of free spaces among the benzene rings the diols exhibit a peculiar intercalation behavior. This behavior is explained on the basis of molecular simulation, which facilitated to elucidate the arrangement of the diol (guest) molecules in the specifically shaped space between the layers of the host material. From thestructural point of view the intercalates can be divided into two subgroups: (i) intercalates with 1,2- to 1,4-diols and (ii) intercalates with 1,6- to 1,8-diols. The alkanediols of the first group are immersed in the free spaces among th

Název v anglickém jazyce

Intercalation of 1,n-diols into strontium phenylphosphonate: How the shape of the host layers influences arrangement of the guest molecules

Popis výsledku anglicky

Strontium phenylphosphonate intercalates with 1,n diols (n = 2-4, 6-8) having general formula SrC6H5PO3 center dot x(HO(CH2)(n)OH)center dot yH(2)O were prepared by precipitation from strontium phenylphosphonate solution and the corresponding diols. Prepared compounds exhibit a very good stability at ambient conditions. The intercalates were characterized by X-ray diffraction, thermogravimetry and elemental analysis. Thanks to the existence of free spaces among the benzene rings the diols exhibit a peculiar intercalation behavior. This behavior is explained on the basis of molecular simulation, which facilitated to elucidate the arrangement of the diol (guest) molecules in the specifically shaped space between the layers of the host material. From thestructural point of view the intercalates can be divided into two subgroups: (i) intercalates with 1,2- to 1,4-diols and (ii) intercalates with 1,6- to 1,8-diols. The alkanediols of the first group are immersed in the free spaces among th

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CI - Průmyslová chemie a chemické inženýrství

OECD FORD obor

—

Projekt

<a href="/cs/project/GA14-13368S" target="_blank" >GA14-13368S: 2D struktury na bázi fosfonátů kovů: vztahy mezi uspořádáním a vlastnostmi studované pomocí experimentálních a výpočetních metod</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Colloid and Interface Science

ISSN

0021-9797

e-ISSN

—

Svazek periodika

460

Číslo periodika v rámci svazku

22 August 2015

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

8

Strana od-do

181-188

Kód UT WoS článku

000363077800022

EID výsledku v databázi Scopus

2-s2.0-84940032456