Additional Phases at High Boron Content in High-Temperature Co-Re-Cr Alloys

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F18%3A10391759" target="_blank" >RIV/00216208:11320/18:10391759 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61389005:_____/18:00493524

Výsledek na webu

<a href="https://doi.org/10.3390/met8080621" target="_blank" >https://doi.org/10.3390/met8080621</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/met8080621" target="_blank" >10.3390/met8080621</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Additional Phases at High Boron Content in High-Temperature Co-Re-Cr Alloys

Popis výsledku v původním jazyce

Boron largely increases the ductility of polycrystalline high-temperature Co-Re-Cr alloys. Therefore, the effect of boron addition on the alloy structural characteristics is of large importance for the stability of the alloy at operational temperatures. Along with the Co-solid solution matrix phase transformation from hcp to fcc structure, additional structural effects were observed in situ at very high temperatures (up to 1500 degrees C) using neutron diffraction (ND) in boron-containing Co-17Re-23Cr alloys. Increasing boron content up to 1000 wt. ppm lowers the temperature at which sublimation of Co and Cr from the matrix occurs. As a result, the composition of the matrix in the surface region is changed leading to the formation of a second and a third matrix hcp phases at high temperatures. The consideration on the lattice parameter dependence on composition was used to identify the new phases appearing at high temperatures. Energy-dispersive spectroscopy and ND results were used to estimate the amount of Co and Cr which sublimated from the surface region of the high-boron sample. In the sense of alloy development, the sublimation of Co and Cr is not critical as the temperature range where it is observed (&gt;= 1430 degrees C) is significantly above the foreseen operation temperature of the alloys (1200 degrees C).

Název v anglickém jazyce

Additional Phases at High Boron Content in High-Temperature Co-Re-Cr Alloys

Popis výsledku anglicky

Boron largely increases the ductility of polycrystalline high-temperature Co-Re-Cr alloys. Therefore, the effect of boron addition on the alloy structural characteristics is of large importance for the stability of the alloy at operational temperatures. Along with the Co-solid solution matrix phase transformation from hcp to fcc structure, additional structural effects were observed in situ at very high temperatures (up to 1500 degrees C) using neutron diffraction (ND) in boron-containing Co-17Re-23Cr alloys. Increasing boron content up to 1000 wt. ppm lowers the temperature at which sublimation of Co and Cr from the matrix occurs. As a result, the composition of the matrix in the surface region is changed leading to the formation of a second and a third matrix hcp phases at high temperatures. The consideration on the lattice parameter dependence on composition was used to identify the new phases appearing at high temperatures. Energy-dispersive spectroscopy and ND results were used to estimate the amount of Co and Cr which sublimated from the surface region of the high-boron sample. In the sense of alloy development, the sublimation of Co and Cr is not critical as the temperature range where it is observed (&gt;= 1430 degrees C) is significantly above the foreseen operation temperature of the alloys (1200 degrees C).

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2018

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Metals

ISSN

2075-4701

e-ISSN

—

Svazek periodika

8

Číslo periodika v rámci svazku

8

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

17

Strana od-do

—

Kód UT WoS článku

000443616400057

EID výsledku v databázi Scopus

2-s2.0-85051498513