Synthesis of 3,3'-substituted[2]staffane derivatives and NMR study of their inclusion complexes with beta-cyclodextrin in water

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F04%3A00010131" target="_blank" >RIV/00216224:14310/04:00010131 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis of 3,3'-substituted[2]staffane derivatives and NMR study of their inclusion complexes with beta-cyclodextrin in water

Popis výsledku v původním jazyce

Derivatives of bicyclo[1.1.1]pentante (BCP) I were recognized as very interesting class of compounds due to their structural features. For example, BCP cage represents a basic construction module for rigid rod like molecules . [n]staffanes II, the fundamental part of suggested molecular size construction set1. Having the set of predefined properties with appropriate tools of supramolecular chemistry in hand, one might be able to construct novel molecular materials. Since practically useful synthesis of[1.1.1]propellane had been found, synthetic aspects of BCP chemistry became relatively developed recently2. On the other hand, there is little known about supramolecular chemistry of BCP derivatives so far. Inspired with Berg et al. (cf.3) describing complexation of bicyclo[2.2.2]octane derivatives with cyclodextrins (CD) and with CD-based pseudo-rotaxane model4 in our minds, we focused our interest to the host-guest chemist

Název v anglickém jazyce

Synthesis of 3,3'-substituted[2]staffane derivatives and NMR study of their inclusion complexes with beta-cyclodextrin in water

Popis výsledku anglicky

Derivatives of bicyclo[1.1.1]pentante (BCP) I were recognized as very interesting class of compounds due to their structural features. For example, BCP cage represents a basic construction module for rigid rod like molecules . [n]staffanes II, the fundamental part of suggested molecular size construction set1. Having the set of predefined properties with appropriate tools of supramolecular chemistry in hand, one might be able to construct novel molecular materials. Since practically useful synthesis of[1.1.1]propellane had been found, synthetic aspects of BCP chemistry became relatively developed recently2. On the other hand, there is little known about supramolecular chemistry of BCP derivatives so far. Inspired with Berg et al. (cf.3) describing complexation of bicyclo[2.2.2]octane derivatives with cyclodextrins (CD) and with CD-based pseudo-rotaxane model4 in our minds, we focused our interest to the host-guest chemist

Druh

D - Stať ve sborníku

CEP obor

CC - Organická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/ME%20571" target="_blank" >ME 571: Substituované bicyklo [1.1.1.] pentany a [n] staffany</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2004

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název statě ve sborníku

Chemické listy, IV. Mezioborové setkání mladých biologů,

ISBN

0009 - 2770

ISSN

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e-ISSN

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Počet stran výsledku

1

Strana od-do

274

Název nakladatele

Česká společnost chemická

Místo vydání

Praha

Místo konání akce

Devět skal - Žďárské vrchy

Datum konání akce

9. 6. 2004

Typ akce podle státní příslušnosti

CST - Celostátní akce

Kód UT WoS článku

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