Bambusurils Bearing Nitro Groups and Their Further Modifications

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F18%3A00100977" target="_blank" >RIV/00216224:14310/18:00100977 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61389013:_____/18:00485574

Výsledek na webu

<a href="https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201701329" target="_blank" >https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201701329</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/ejoc.201701329" target="_blank" >10.1002/ejoc.201701329</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Bambusurils Bearing Nitro Groups and Their Further Modifications

Popis výsledku v původním jazyce

Bambusurils are recently developed neutral anion receptors that show a high affinity towards many inorganic anions, not only in organic solvents but also in water. However, the number of water-soluble bambusurils and also those bearing functional groups is very limited. In this paper we report the synthesis of four- and six-membered bambusurils containing eight and twelve nitro groups. All the nitro groups on the bambusuril portals could be transformed into amino functions, which provided the macrocycles with water solubility and allowed their further modification. For example, we have demonstrated the conversion of amino groups on the bambusurils into the corresponding urea-functionalized bambusuril derivatives. We also report the first example of a bambusuril bearing only two functional groups, which was prepared by the condensation of two different glycolurils.

Název v anglickém jazyce

Bambusurils Bearing Nitro Groups and Their Further Modifications

Popis výsledku anglicky

Bambusurils are recently developed neutral anion receptors that show a high affinity towards many inorganic anions, not only in organic solvents but also in water. However, the number of water-soluble bambusurils and also those bearing functional groups is very limited. In this paper we report the synthesis of four- and six-membered bambusurils containing eight and twelve nitro groups. All the nitro groups on the bambusuril portals could be transformed into amino functions, which provided the macrocycles with water solubility and allowed their further modification. For example, we have demonstrated the conversion of amino groups on the bambusurils into the corresponding urea-functionalized bambusuril derivatives. We also report the first example of a bambusuril bearing only two functional groups, which was prepared by the condensation of two different glycolurils.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10401 - Organic chemistry

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2018

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

European Journal of Organic Chemistry

ISSN

1434-193X

e-ISSN

—

Svazek periodika

Neuveden

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

7

Strana od-do

41-47

Kód UT WoS článku

000419707900005

EID výsledku v databázi Scopus

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