Quenching of an Aniline Radical Cation by Dissolved Organic Matter and Phenols: A Laser Flash Photolysis Study
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F20%3A00114580" target="_blank" >RIV/00216224:14310/20:00114580 - isvavai.cz</a>
Výsledek na webu
<a href="https://doi.org/10.1021/acs.est.0c05230" target="_blank" >https://doi.org/10.1021/acs.est.0c05230</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.est.0c05230" target="_blank" >10.1021/acs.est.0c05230</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Quenching of an Aniline Radical Cation by Dissolved Organic Matter and Phenols: A Laser Flash Photolysis Study
Popis výsledku v původním jazyce
Aromatic amines are relevant aquatic organic contaminants whose photochemical transformation is affected by dissolved organic matter (DOM). The goal of this study is to elucidate the underlying mechanism of the inhibitory effect of DOM on such reactions. The selected model aromatic amine, 4-(dimethylamino)benzonitrile (DMABN), was subjected to laser flash photolysis in the presence and absence of various model photosensitizers. The produced radical cation (DMABN(.+)) was observed to react with several phenols and different types of DOM on a time scale of similar to 100 mu s. The determined second-order rate constants for the quenching of DMABN(.+) by phenols were in the range of (1.4-26) X 10(8) M-1 s(-1) and increased with increasing electron donor character of the aromatic ring substituent. For DOM, quenching rate constants increased with the phenolic content of the DOM. These results indicate the reduction of DMABN(.+) to re-form its parent compound as the basic reaction governing the inhibitory effect. In addition, the photosensitized oxidation of the sulfonamide antibiotic sulfadiazine (SDZ) was studied. The observed radical intermediate of SDZ was quenched by 4-methoxyphenol less effectively than DMABN(.+), which was attributed to the lower reduction potential of the SDZ-derived radical compared to DMABN(.+).
Název v anglickém jazyce
Quenching of an Aniline Radical Cation by Dissolved Organic Matter and Phenols: A Laser Flash Photolysis Study
Popis výsledku anglicky
Aromatic amines are relevant aquatic organic contaminants whose photochemical transformation is affected by dissolved organic matter (DOM). The goal of this study is to elucidate the underlying mechanism of the inhibitory effect of DOM on such reactions. The selected model aromatic amine, 4-(dimethylamino)benzonitrile (DMABN), was subjected to laser flash photolysis in the presence and absence of various model photosensitizers. The produced radical cation (DMABN(.+)) was observed to react with several phenols and different types of DOM on a time scale of similar to 100 mu s. The determined second-order rate constants for the quenching of DMABN(.+) by phenols were in the range of (1.4-26) X 10(8) M-1 s(-1) and increased with increasing electron donor character of the aromatic ring substituent. For DOM, quenching rate constants increased with the phenolic content of the DOM. These results indicate the reduction of DMABN(.+) to re-form its parent compound as the basic reaction governing the inhibitory effect. In addition, the photosensitized oxidation of the sulfonamide antibiotic sulfadiazine (SDZ) was studied. The observed radical intermediate of SDZ was quenched by 4-methoxyphenol less effectively than DMABN(.+), which was attributed to the lower reduction potential of the SDZ-derived radical compared to DMABN(.+).
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10403 - Physical chemistry
Návaznosti výsledku
Projekt
<a href="/cs/project/GA19-08239S" target="_blank" >GA19-08239S: Spektroskopie a mikroskopie chemických látek v ledu pro environmentální a farmaceutické účely</a><br>
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Ostatní
Rok uplatnění
2020
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Environmental Science and Technology
ISSN
0013-936X
e-ISSN
1520-5851
Svazek periodika
54
Číslo periodika v rámci svazku
23
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
9
Strana od-do
15057-15065
Kód UT WoS článku
000596728600032
EID výsledku v databázi Scopus
2-s2.0-85096560900