Acoustic signal in overcoming the matrix effect in LIBS: Toward reliable applicability

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F25%3A00141960" target="_blank" >RIV/00216224:14310/25:00141960 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0584854725000254?via%3Dihub#ac0005" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0584854725000254?via%3Dihub#ac0005</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.sab.2025.107140" target="_blank" >10.1016/j.sab.2025.107140</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Acoustic signal in overcoming the matrix effect in LIBS: Toward reliable applicability

Popis výsledku v původním jazyce

The versatility of laser-induced breakdown spectroscopy (LIBS) resulting from its advantageous analytical characteristics is, unfortunately, still limited by challenges inherent to the fundamental principles of the method - the processes of laser ablation and laser-induced plasma generation. Unwanted effects (generally known as matrix effects) significantly decrease the analytical performance of LIBS, complicating quantification and impairing reproducibility. This study investigates acoustic signals accompanying plasmas (LIPAc) to overcome these limitations and enhance LIBS performance. The influence of instrumental (microphone types), operational (laser wavelength and fluence) and sample parameters on acoustic responses were evaluated. The results indicate that laser fluence strongly influences acoustic wave oscillation. When laser fluence substantially exceeds the breakdown thresholds of the different components in the matter, acoustic responses may become identical across various materials. On the other hand, proportionality in differences of acoustic signal is maintained for different microphones and laser wavelength settings. Promising solutions for eliminating matrix effects on various surfaces were identified, but the suitability and efficiency may be highly dependent on the emission line used. This is demonstrated using the signals of atomic Cu(I) 324.74 nm and ionic Cu(II) 329.04 nm lines measured from an aluminum sample with a partially coppered and partially roughened surface. Acoustic maps of a galena ore sample demonstrate the applications of LIPAc in spatially resolved LIBS imaging and elemental mapping. These maps can help eliminate the discrepancy between the intensities of the calcium atomic line of Ca(I) at 422.67 nm measured from the galena mineral and calcium carbonate.

Název v anglickém jazyce

Acoustic signal in overcoming the matrix effect in LIBS: Toward reliable applicability

Popis výsledku anglicky

The versatility of laser-induced breakdown spectroscopy (LIBS) resulting from its advantageous analytical characteristics is, unfortunately, still limited by challenges inherent to the fundamental principles of the method - the processes of laser ablation and laser-induced plasma generation. Unwanted effects (generally known as matrix effects) significantly decrease the analytical performance of LIBS, complicating quantification and impairing reproducibility. This study investigates acoustic signals accompanying plasmas (LIPAc) to overcome these limitations and enhance LIBS performance. The influence of instrumental (microphone types), operational (laser wavelength and fluence) and sample parameters on acoustic responses were evaluated. The results indicate that laser fluence strongly influences acoustic wave oscillation. When laser fluence substantially exceeds the breakdown thresholds of the different components in the matter, acoustic responses may become identical across various materials. On the other hand, proportionality in differences of acoustic signal is maintained for different microphones and laser wavelength settings. Promising solutions for eliminating matrix effects on various surfaces were identified, but the suitability and efficiency may be highly dependent on the emission line used. This is demonstrated using the signals of atomic Cu(I) 324.74 nm and ionic Cu(II) 329.04 nm lines measured from an aluminum sample with a partially coppered and partially roughened surface. Acoustic maps of a galena ore sample demonstrate the applications of LIPAc in spatially resolved LIBS imaging and elemental mapping. These maps can help eliminate the discrepancy between the intensities of the calcium atomic line of Ca(I) at 422.67 nm measured from the galena mineral and calcium carbonate.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10406 - Analytical chemistry

Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2025

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY

ISSN

0584-8547

e-ISSN

1873-3565

Svazek periodika

226

Číslo periodika v rámci svazku

APR

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

12

Strana od-do

1-12

Kód UT WoS článku

001426626100001

EID výsledku v databázi Scopus

2-s2.0-85217418800