Organometalické kationtové iniciátory UV barev

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F06%3A00004660" target="_blank" >RIV/00216275:25310/06:00004660 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Organometalic Cationic Initiators for UV Inks

Popis výsledku v původním jazyce

A several new arene-iron complexes were prepared by the treatment of chlorobenzene with ferrocene in the presence of aluminium. The obtained chloroaluminate complexes were converted into hexafluorophosphates by treatment with aqueous solution of hexafluorophosphate salt. The hexafluorophosphate complexes are easier to store and handle. These compounds were characterized by NMR and MS spectroscopy. The UV light decomposes arene-ironcyclopentadienyl (arene-FeCp+) cation selectively to the corresponding aromatic compound and iron cyclopentadiene (CpFe+) cation. During irradiation formed FeCp+ is the active species for cationic polymerization. The polymerization activities of prepared arene-FeCp+ complexes for epoxide and vinylether monomers were measuredby FTIR spectroscopy. The solubility of prepared compounds in the monomer is limited factor for application of these compounds.

Název v anglickém jazyce

Organometalic Cationic Initiators for UV Inks

Popis výsledku anglicky

A several new arene-iron complexes were prepared by the treatment of chlorobenzene with ferrocene in the presence of aluminium. The obtained chloroaluminate complexes were converted into hexafluorophosphates by treatment with aqueous solution of hexafluorophosphate salt. The hexafluorophosphate complexes are easier to store and handle. These compounds were characterized by NMR and MS spectroscopy. The UV light decomposes arene-ironcyclopentadienyl (arene-FeCp+) cation selectively to the corresponding aromatic compound and iron cyclopentadiene (CpFe+) cation. During irradiation formed FeCp+ is the active species for cationic polymerization. The polymerization activities of prepared arene-FeCp+ complexes for epoxide and vinylether monomers were measuredby FTIR spectroscopy. The solubility of prepared compounds in the monomer is limited factor for application of these compounds.

Druh

D - Stať ve sborníku

CEP obor

CD - Makromolekulární chemie

OECD FORD obor

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Projekt

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Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2006

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název statě ve sborníku

Book of Abstracts (+ Conference Proceedings CD)

ISBN

961-6045-35-0

ISSN

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e-ISSN

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Počet stran výsledku

4

Strana od-do

142

Název nakladatele

University of Ljubljana

Místo vydání

Ljubljana, Slovenia

Místo konání akce

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Datum konání akce

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Typ akce podle státní příslušnosti

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Kód UT WoS článku

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