Systematic Method for the Incorporation of the {(eta(6)-Arene)Fe} Fragment into Carborane Cages via [(eta(6)-Arene)Fe](2+) Dications. A Series of [3-(eta(6)-Arene)-closo-3,1,2-FeC2B9H11] Complexes. Reliable Synthesis of Polymethylated [(eta(6)-Arene)

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F09%3A00008337" target="_blank" >RIV/00216275:25310/09:00008337 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61388980:_____/09:00340428

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Systematic Method for the Incorporation of the {(eta(6)-Arene)Fe} Fragment into Carborane Cages via [(eta(6)-Arene)Fe](2+) Dications. A Series of [3-(eta(6)-Arene)-closo-3,1,2-FeC2B9H11] Complexes. Reliable Synthesis of Polymethylated [(eta(6)-Arene)

Popis výsledku v původním jazyce

Developed was a systematic method for the incorporation of the {(eta(6)-arene)Fe} fragment into a carborane cage. Reactions between [(eta(6)-arene)(2)Fe](PF6)(2) salts and Tl-2[nido-7,8-C2B9H11] in refluxing (CH2)(2)Cl-2 generated a series of [3-(eta(6)-arene)-closo-3,1,2-FeC2B9H11] neutral complexes with variable types of polymethylated arene ligands in the structure. The structures of durene and hexamethylbenzene complexes were established by X-ray diffraction analyses. The work also shows that the original hi temperature method for the preparation of the [(eta(6)-arene)(2)Fe](2+) dications fails for mesitylene and durene compounds, which was overcome by a reliable room-temperature modification.

Název v anglickém jazyce

Systematic Method for the Incorporation of the {(eta(6)-Arene)Fe} Fragment into Carborane Cages via [(eta(6)-Arene)Fe](2+) Dications. A Series of [3-(eta(6)-Arene)-closo-3,1,2-FeC2B9H11] Complexes. Reliable Synthesis of Polymethylated [(eta(6)-Arene)

Popis výsledku anglicky

Developed was a systematic method for the incorporation of the {(eta(6)-arene)Fe} fragment into a carborane cage. Reactions between [(eta(6)-arene)(2)Fe](PF6)(2) salts and Tl-2[nido-7,8-C2B9H11] in refluxing (CH2)(2)Cl-2 generated a series of [3-(eta(6)-arene)-closo-3,1,2-FeC2B9H11] neutral complexes with variable types of polymethylated arene ligands in the structure. The structures of durene and hexamethylbenzene complexes were established by X-ray diffraction analyses. The work also shows that the original hi temperature method for the preparation of the [(eta(6)-arene)(2)Fe](2+) dications fails for mesitylene and durene compounds, which was overcome by a reliable room-temperature modification.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/LC523" target="_blank" >LC523: Perspektivní anorganické materiály</a><br>

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2009

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Inorganic Chemistry

ISSN

0020-1669

e-ISSN

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Svazek periodika

48

Číslo periodika v rámci svazku

23

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

3

Strana od-do

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Kód UT WoS článku

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EID výsledku v databázi Scopus

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