Synthesis, Structure and Transmetalation Activity of Various C,Y-Chelated Organogold(I) Compounds

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F12%3A39895559" target="_blank" >RIV/00216275:25310/12:39895559 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1002/ejic.201200152" target="_blank" >http://dx.doi.org/10.1002/ejic.201200152</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/ejic.201200152" target="_blank" >10.1002/ejic.201200152</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis, Structure and Transmetalation Activity of Various C,Y-Chelated Organogold(I) Compounds

Popis výsledku v původním jazyce

A set of organogold(I) compounds L14Au(PPh3), where L1 = [o-C6H4(CH=NC6H3iPr2-2,6)] (1), L2 = {o,o-C6H3[C(Me)=NC6H3Me2-2,6]2} (2), L3 = [o,o'-C6H3(CH2OMe)(CH2NMe2)] (3), L4 = [o,o-C6H3(CH2OMe)2] (4), were synthesized by the reaction of parent organolithium derivatives L14Li with [AuCl(PPh3)] in good yields. The molecular structures of 14 were characterized by ESI mass spectrometry and 1H NMR, 13C NMR and 31P NMR spectroscopy, and their structures in the solid state were determined using single-crystal X-ray diffraction analyses. The transmetalation potential of 14 was tested by the reaction with either [PdCl2(CH3CN)2] or [PtCl2(Et2S)2] complexes. While the reaction of compounds 1 and 2 proceeded smoothly with the formation of the desired transition-metal complexes, i.e. (L1PdCl)2 (5), L1PtCl(Et2S) (6) and L2MCl [M = Pd (7) or Pt (8). In the case of the O,C,N- and O,C,O-chelated derivatives 3 and 4 only the platinum(II) compounds L3PtCl(PPh3) (9) and L4PtCl(Et2S)2 (10) could be isolated

Název v anglickém jazyce

Synthesis, Structure and Transmetalation Activity of Various C,Y-Chelated Organogold(I) Compounds

Popis výsledku anglicky

A set of organogold(I) compounds L14Au(PPh3), where L1 = [o-C6H4(CH=NC6H3iPr2-2,6)] (1), L2 = {o,o-C6H3[C(Me)=NC6H3Me2-2,6]2} (2), L3 = [o,o'-C6H3(CH2OMe)(CH2NMe2)] (3), L4 = [o,o-C6H3(CH2OMe)2] (4), were synthesized by the reaction of parent organolithium derivatives L14Li with [AuCl(PPh3)] in good yields. The molecular structures of 14 were characterized by ESI mass spectrometry and 1H NMR, 13C NMR and 31P NMR spectroscopy, and their structures in the solid state were determined using single-crystal X-ray diffraction analyses. The transmetalation potential of 14 was tested by the reaction with either [PdCl2(CH3CN)2] or [PtCl2(Et2S)2] complexes. While the reaction of compounds 1 and 2 proceeded smoothly with the formation of the desired transition-metal complexes, i.e. (L1PdCl)2 (5), L1PtCl(Et2S) (6) and L2MCl [M = Pd (7) or Pt (8). In the case of the O,C,N- and O,C,O-chelated derivatives 3 and 4 only the platinum(II) compounds L3PtCl(PPh3) (9) and L4PtCl(Et2S)2 (10) could be isolated

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GAP207%2F10%2F0215" target="_blank" >GAP207/10/0215: Struktura, vlastnosti a využití C,N-, a Y,C,Y-chelatovaných organokovových sloučenin a podobných komplexů kovů</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2012

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

European Journal of Inorganic Chemistry

ISSN

1434-1948

e-ISSN

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Svazek periodika

Neuveden

Číslo periodika v rámci svazku

15

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

10

Strana od-do

2578-2587

Kód UT WoS článku

000303987800011

EID výsledku v databázi Scopus

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