Addition of Lappert's stannylenes to carbodiimides, providing a new class of tin(II) guanidinates

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F12%3A39895768" target="_blank" >RIV/00216275:25310/12:39895768 - isvavai.cz</a>

Výsledek na webu

<a href="http://pubs.acs.org/doi/abs/10.1021/om201118m" target="_blank" >http://pubs.acs.org/doi/abs/10.1021/om201118m</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/om201118m" target="_blank" >10.1021/om201118m</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Addition of Lappert's stannylenes to carbodiimides, providing a new class of tin(II) guanidinates

Popis výsledku v původním jazyce

Reactions of bis[bis(trimethylsilyl)amino]tin and the dimer of [bis(trimethylsilyl)amino]tin chloride with various carbodiimides give pure corresponding tin(II) guanidinates in essentially quantitative yields. Heteroleptic bis(trimethylsilyl)amido ({R-NC[N-(SiMe3)(2)]N-R}SnN(SiMe3)(2))- and chloro-substituted ({R-NC}[N-(SiMe3)(2)]N-R}SnCl) tin(II) guanidinates were obtained from reactions of N,N'-diisopropyl-, N,N'-dicyclohexyl-, N,N'-bis(4-methylphenyl)-, and N-[3-(dimethylamino)propyl]-N'-ethylcarbodiimides, respectively. Homoleptic tin(II) guanidinates {R-NC[N(SiMe3)(2)]N-R}(2)Sn were obtained from the N,N'-bis(4-methylphenyl)- and N-[3-(dimethylamino)propyl]-N'-ethyl-substituted carbodiimides. Similar reactions of N,N'-bis(2,6-diisopropylphenyl)- and N,N'-bis(trimethylsilyl)carbodiimide, respectively, having the bulkiest substituents of the series, failed to take place under various conditions. The complexes prepared were characterized as monomers in solution by H-1, C-13, and Sn-1

Název v anglickém jazyce

Addition of Lappert's stannylenes to carbodiimides, providing a new class of tin(II) guanidinates

Popis výsledku anglicky

Reactions of bis[bis(trimethylsilyl)amino]tin and the dimer of [bis(trimethylsilyl)amino]tin chloride with various carbodiimides give pure corresponding tin(II) guanidinates in essentially quantitative yields. Heteroleptic bis(trimethylsilyl)amido ({R-NC[N-(SiMe3)(2)]N-R}SnN(SiMe3)(2))- and chloro-substituted ({R-NC}[N-(SiMe3)(2)]N-R}SnCl) tin(II) guanidinates were obtained from reactions of N,N'-diisopropyl-, N,N'-dicyclohexyl-, N,N'-bis(4-methylphenyl)-, and N-[3-(dimethylamino)propyl]-N'-ethylcarbodiimides, respectively. Homoleptic tin(II) guanidinates {R-NC[N(SiMe3)(2)]N-R}(2)Sn were obtained from the N,N'-bis(4-methylphenyl)- and N-[3-(dimethylamino)propyl]-N'-ethyl-substituted carbodiimides. Similar reactions of N,N'-bis(2,6-diisopropylphenyl)- and N,N'-bis(trimethylsilyl)carbodiimide, respectively, having the bulkiest substituents of the series, failed to take place under various conditions. The complexes prepared were characterized as monomers in solution by H-1, C-13, and Sn-1

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2012

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Organometallics

ISSN

0276-7333

e-ISSN

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Svazek periodika

31

Číslo periodika v rámci svazku

6

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

9

Strana od-do

2203-2211

Kód UT WoS článku

000301895900010

EID výsledku v databázi Scopus

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