Acyl-Functionalized Molybdenum Compounds [(éta3-C3H5)(éta5-Cp)Mo(CO)2]: An Experimental Study Including the X-ray Structure of a Rare endo Conformer

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898091" target="_blank" >RIV/00216275:25310/14:39898091 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1002/ejic.201402700" target="_blank" >http://dx.doi.org/10.1002/ejic.201402700</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/ejic.201402700" target="_blank" >10.1002/ejic.201402700</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Acyl-Functionalized Molybdenum Compounds [(éta3-C3H5)(éta5-Cp)Mo(CO)2]: An Experimental Study Including the X-ray Structure of a Rare endo Conformer

Popis výsledku v původním jazyce

A series of new acyl-functionalized molybdenum(II) complexes [(éta3-C3H5)(éta5-C5H4COR)Mo(CO)2] have been successfully synthesized and crystallographically characterized, and the relationship between the reactivity and electronic properties of these organometallic compounds has been studied in detail. The X-ray analysis revealed [(éta3-C3H5)(éta5-C5H4COCF3)Mo(CO)2] to exist as a rare endo conformer, the first time that this structure has been observed in the crystal lattice of a [(éta3-C3H5)(éta5-Cp?)Mo(CO)2] (Cp? = substituted Cp) complex without any disorder. It has also been demonstrated that the derivatives bearing very strong electron-withdrawing acyl groups (e.g., -CHO, -COCF3) show different outcomes in the protonation reactions compared with the parent cyclopentadienyl compound or derivatives bearing less electron-withdrawing groups (e.g., -COMe, -COPh). This study has also revealed the increased reactivity of the formyl derivative [(éta3-C3H5)(éta5-C5H4CHO)Mo(CO)2] towards aro

Název v anglickém jazyce

Acyl-Functionalized Molybdenum Compounds [(éta3-C3H5)(éta5-Cp)Mo(CO)2]: An Experimental Study Including the X-ray Structure of a Rare endo Conformer

Popis výsledku anglicky

A series of new acyl-functionalized molybdenum(II) complexes [(éta3-C3H5)(éta5-C5H4COR)Mo(CO)2] have been successfully synthesized and crystallographically characterized, and the relationship between the reactivity and electronic properties of these organometallic compounds has been studied in detail. The X-ray analysis revealed [(éta3-C3H5)(éta5-C5H4COCF3)Mo(CO)2] to exist as a rare endo conformer, the first time that this structure has been observed in the crystal lattice of a [(éta3-C3H5)(éta5-Cp?)Mo(CO)2] (Cp? = substituted Cp) complex without any disorder. It has also been demonstrated that the derivatives bearing very strong electron-withdrawing acyl groups (e.g., -CHO, -COCF3) show different outcomes in the protonation reactions compared with the parent cyclopentadienyl compound or derivatives bearing less electron-withdrawing groups (e.g., -COMe, -COPh). This study has also revealed the increased reactivity of the formyl derivative [(éta3-C3H5)(éta5-C5H4CHO)Mo(CO)2] towards aro

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

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Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2014

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

European Journal of Inorganic Chemistry

ISSN

1434-1948

e-ISSN

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Svazek periodika

Neuveden

Číslo periodika v rámci svazku

34

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

13

Strana od-do

5895-5907

Kód UT WoS článku

000345771700012

EID výsledku v databázi Scopus

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