Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898096" target="_blank" >RIV/00216275:25310/14:39898096 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.jorganchem.2014.09.028" target="_blank" >http://dx.doi.org/10.1016/j.jorganchem.2014.09.028</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jorganchem.2014.09.028" target="_blank" >10.1016/j.jorganchem.2014.09.028</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands

Popis výsledku v původním jazyce

The reactivity of cyclopentadienyl and indenyl molybdenum(II) complexes [(h5-Cp')Mo(CO)2(NCMe)2] [BF4] (Cp' = Cp, Ind, 1,3-Ph2C9H5) with a series of planar N,N,N-chelating ligands was scrutinized. In particular cases a spontaneous release of carbon monoxide to give [(h5-Cp')Mo(CO)(k3-N,N,NL)][BF4] depending on several factors including the basicity of the tridentate ligand as well as the nature of the starting molybdenum(II) compound. This behaviour strongly contrasts with tripodal ligands those do notaffect cis-Mo(CO)2 moiety even upon tridentate coordination. All structure types, discussed in this work, were elucidated by the spectroscopic measurements as well as by the X-ray crystallography.

Název v anglickém jazyce

Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands

Popis výsledku anglicky

The reactivity of cyclopentadienyl and indenyl molybdenum(II) complexes [(h5-Cp')Mo(CO)2(NCMe)2] [BF4] (Cp' = Cp, Ind, 1,3-Ph2C9H5) with a series of planar N,N,N-chelating ligands was scrutinized. In particular cases a spontaneous release of carbon monoxide to give [(h5-Cp')Mo(CO)(k3-N,N,NL)][BF4] depending on several factors including the basicity of the tridentate ligand as well as the nature of the starting molybdenum(II) compound. This behaviour strongly contrasts with tripodal ligands those do notaffect cis-Mo(CO)2 moiety even upon tridentate coordination. All structure types, discussed in this work, were elucidated by the spectroscopic measurements as well as by the X-ray crystallography.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

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Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2014

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Organometallic Chemistry

ISSN

0022-328X

e-ISSN

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Svazek periodika

772-773

Číslo periodika v rámci svazku

December

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

8

Strana od-do

299-306

Kód UT WoS článku

000344470100040

EID výsledku v databázi Scopus

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